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Mimaki Y, Ori K, Sashida Y, Nikaido T, Song LG, Ohmoto T
Peruvianosides A and B, novel triterpene glycosides from the bulbs of Scilla peruviana
Bulletin of the Chemical Society of Japan 66 (1993)
1182-1186
|
a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Subst
Subst = peruvianoside B aglycon = SMILES C[C@@H]({17}[C@@]1(O)[C@@H](O{23}[C@H]2O)C[C@@]3([C@]1(C)CCC4=C3CC[C@H]5[C@](C)({3}[C@H](CC[C@]45C)O){31}CO)C)[C@H]2/C=C(C)/C(OC)=O |
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Scilla peruviana
(NCBI TaxID 65771,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: bulb
The structure was elucidated in this paperPublication DOI: 10.1246/bcsj.66.1182Journal NLM ID: 7505371Publisher: Tokyo: Nippon Kagakukai
Institutions: Tokyo College of Pharmacy, Tokyo, Japan, School of Pharmaceutical Sciences, Toho University, Japan
Two new rearranged lanosterol trisaccharides, peruvianosides A (1) and B (2), were isolated from fresh bulbs of Scilla peruviana. Their structures were established mainly by extensive 2D NMR analysis. Peruvianoside A (1) showed an inhibitory activity on cyclic adenosine monophosphate (AMP) phosphodiesterase.
Structure type: oligomer
Location inside paper: 2
Trivial name: peruvianoside B
Compound class: steroid glycoside
Contained glycoepitopes: IEDB_136105,IEDB_140628,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, FAB-MS, acid hydrolysis, optical rotation measurement, acetylation, NMR 2D, assay of cyclip AMP phosphodiesterase activity
Related record ID(s): 161970
NCBI Taxonomy refs (TaxIDs): 65771Reference(s) to other database(s): CCSD:
45791, CBank-STR:7625, CA:149155-15-7
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Mimaki Y, Ori K, Sashida Y, Nikaido T, Song LG, Ohmoto T
Peruvianosides A and B, novel triterpene glycosides from the bulbs of Scilla peruviana
Bulletin of the Chemical Society of Japan 66 (1993)
1182-1186
|
a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Subst
Subst = peruvianoside A aglycon = SMILES C[C@@H]({17}[C@@]1(O)[C@@H](O{23}[C@H]2O)C[C@@]3([C@]1(C)CCC4=C3CC[C@H]5C(C)({3}[C@H](CC[C@]45C)O)C)C)[C@H]2/C=C(C)/C(OC)=O |
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Scilla peruviana
(NCBI TaxID 65771,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: bulb
The structure was elucidated in this paperPublication DOI: 10.1246/bcsj.66.1182Journal NLM ID: 7505371Publisher: Tokyo: Nippon Kagakukai
Institutions: Tokyo College of Pharmacy, Tokyo, Japan, School of Pharmaceutical Sciences, Toho University, Japan
Two new rearranged lanosterol trisaccharides, peruvianosides A (1) and B (2), were isolated from fresh bulbs of Scilla peruviana. Their structures were established mainly by extensive 2D NMR analysis. Peruvianoside A (1) showed an inhibitory activity on cyclic adenosine monophosphate (AMP) phosphodiesterase.
Structure type: oligomer
Location inside paper: 1
Trivial name: peruvianoside A
Compound class: steroid glycoside
Contained glycoepitopes: IEDB_136105,IEDB_140628,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, FAB-MS, acid hydrolysis, optical rotation measurement, acetylation, NMR 2D, assay of cyclip AMP phosphodiesterase activity
Related record ID(s): 111970, 161971
NCBI Taxonomy refs (TaxIDs): 65771Reference(s) to other database(s): CCSD:
45791, CBank-STR:7625, CA:145567-94-8
Show glycosyltransferases
There is only one chemically distinct structure:
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