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1. (Article ID: 10471)
Sawada H, Miyakoshi M, Isoda S, Ida Y, Shoji J
Saponins from leaves of Acanthopanax sieboldianus
Phytochemistry 34 (1993)
1117-1121
Two new triterpenoid saponins named sieboldianoside A and B were isolated from the leaves of Acanthopanax sieboldianus together with five known triterpenoid saponins, kalopanax-saponins A and B, saponin A, CP3, sapindoside B, and a known flavonol glycoside, kaempferol 3-O-rutinoside. On the basis of chemical and spectral evidence, the structures of the new saponins (sieboldianoside A and B) were concluded to be α-L-rhamnopyranosyl(1→4)-β-D-glucopyranosyl(1→6)- β-D-glucopyranosyl esters of hederagenin and oleanolic acid 3-O-β-D- xylopyranosyl(1→3)-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosides, respectively.
NCBI PubMed ID: 7764238Journal NLM ID: 0151434Publisher: Elsevier
Institutions: School of Pharmaceutical Sciences, Showa University, Tokyo, Japan
The publication contains the following compound(s):
- Compound ID: 25703
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b-D-Xylp-(1-3)-a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Hederagenin |
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Structure type: oligomer
Trivial name: sieboldianoside A
Compound class: saponin glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
30430, CBank-STR:14377
- Compound ID: 25704
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b-D-Xylp-(1-3)-a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
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Structure type: oligomer
Trivial name: sieboldianoside B
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
5528, CBank-STR:14376
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2. (Article ID: 12202)
Grishkovets VI, Pyatygin AM, Chirva VY
Triterpene glycosides from leaves of Acanthopanax sieboldianus introduced to Ukraine and Crimea
Chemistry of Natural Compounds 36(3) (2000)
325-326
The glycoside composition of A. sieboldianus (Eleutherococcus sieboldianus) leaves collected in Kiev, L'vov, and Simferopol, Ukraine, was studied and compared with that of leaves collected from the natural habitat. Total acid hydrolysis of the leaf extract and TLC analysis of the resulting aglycones showed a large quantity of hederagenin glycosides and a small quantity of oleanolic and echinocystic acid glycosides. The chemical structures of these triterpene glycosides are presented.
glycoside, triterpene glycoside, organic chemistry, Acanthopanax sieboldianus
Publication DOI: 10.1007/BF02238349Journal NLM ID: 0047757Publisher: New York: Kluwer Academic/Plenum Publishers
Institutions: V. I. Vernadskii Tavricheskii National University, Simferopol'
Methods: 13C NMR, TLC, acid hydrolysis, extraction, CC, evaporation
The publication contains the following compound(s):
- Compound ID: 23948
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a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Hederagenin |
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Structure type: oligomer
C53H86O22
Trivial name: Kizutasaponin, pericarpsaponin PJ3
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
39888, CBank-STR:9263
- Compound ID: 23949
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a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Hederagenin |
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Structure type: oligomer
C59H96O26
Trivial name: Kizutasaponin, Kalopanax-saponin B, kalopanax-saponin B, kalopanaxsaponin B, Kizutasaponin K12, hederasaponin C
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
5523, CBank-STR:11737
- Compound ID: 23964
Structure type: oligomer
C41H66O12
Trivial name: Kalopanax-saponin A, α-hederin, kalopanaxsaponin A
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
39886, CBank-STR:2464
- Compound ID: 27071
Structure type: monomer
C35H56O8
Trivial name: akeboside Stb, leontoside A, PA (seed saponin A), β2-fatsin, fatsiaside B1, koelreuteria saponin A, δ-hederin
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
48757, CBank-STR:525
- Compound ID: 30392
Structure type: oligomer
Trivial name: β-hederin
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
- Compound ID: 30394
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a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Oleanolic |
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Structure type: oligomer
Trivial name: hederasaponin B
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
- Compound ID: 30397
Structure type: oligomer
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
- Compound ID: 30401
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a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Echinocystic |
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Structure type: oligomer
Compound class: saponin glycoside, glycoside, triterpenoid glycoside
- Compound ID: 31673
Structure type: oligomer
Compound class: glycoside, triterpenoid glycoside
- Compound ID: 31674
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b-D-Xylp-(1-3)-a-L-Rhap-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Oleanolic |
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Structure type: oligomer
Compound class: glycoside, triterpenoid glycoside
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