Taxonomic group: bacteria / Proteobacteria
(Phylum: Proteobacteria)
Associated disease: infection due to Escherichia coli [ICD11:
XN6P4 
]
The structure was elucidated in this paperNCBI PubMed ID: 8495449Journal NLM ID: 0043535Publisher: Elsevier
Institutions: N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow.
A stepwise approach has been used in the syntheses of pentamannosyl tetraphosphate HO-[-6Man(α)-PO4-]4-6Man(α)-OMe and tetra(N-acetylglucosaminyl) triphosphate HO-[-3GlcNAc(α)-PO4]3- 3GlcNAc(β)-OC6H4NO2, which are fragments of the yeast and bacteria extracellular phosphoglycans. Elongation of the chain was performed with the use of suitably protected glycosyl hydrogenphosphonate derivatives for successive introduction of glycosyl phosphate residues. Partially protected monosaccharide derivatives and oligomeric blocks served as hydroxylic components.
synthesis, antigen, oligosaccharide, capsular, polysaccharide, repeating unit, trisaccharide, Escherichia, Escherichia coli, O-antigenic, O-antigenic polysaccharide, phosphate, Oligosaccharides, chemical, fragment, block synthesis, glycosyl, chemical synthesis, Phosphates
Structure type: oligomer
Location inside paper: p.93, 2
Aglycon: C6H4NO2
Trivial name: fragment of CPS
Compound class: CPS
Contained glycoepitopes: IEDB_135813,IEDB_137340,IEDB_141807,IEDB_150077,IEDB_151531
Methods: 13C NMR, 1H NMR, TLC, 31P NMR, chemical methods
Synthetic data: chemical
NCBI Taxonomy refs (TaxIDs): 562Reference(s) to other database(s): GTC:G07902IQ, GlycomeDB:
6395
Show glycosyltransferases
There is only one chemically distinct structure: