Taxonomic group: fungi / Basidiomycota
(Phylum: Basidiomycota)
Organ / tissue: fruiting body
The structure was elucidated in this paperPublication DOI: 10.1016/j.bcdf.2013.10.005Journal NLM ID: 101628882Publisher: Amsterdam: Elsevier
Correspondence: de Soares SA <sas

ufc.br>
Institutions: Departament of Organic and Inorganic Chemistry, Federal University of Ceará, Fortaleza, Ceará, Brazil
Many interesting biological activities have been reported related to the presence of β-glucans from different species of mushrooms. In this work, β-glucans were isolated from the polysaccharide of the fruiting bodies of Agaricus blazei Murill known as Agaricus brasiliensis. β-Glucans were obtained with a specific procedure using thymol. The isolated material was characterized by FTIR assignments which indicate the presence of polysaccharides and some amount of protein in the obtained precipitate. The presence of β-glucans was evidenced by recording the band around 890 cm-1 relative to the deformation of that bond. 1H and 13C NMR as well as two-dimensional COSY and HMQC spectra were used for characterization of the β-glucans which showed that the isolated material is constituted mainly by β-(1-6) glucans.
NMR, FTIR, Agaricus blazei Murill, β-glucan-protein complex
Structure type: structural motif or average structure
Location inside paper: fig. 1
Trivial name: β-1,6-glucan
Compound class: EPS, cell wall polysaccharide, glucan
Contained glycoepitopes: IEDB_135614,IEDB_141806,IEDB_142488,IEDB_146664,IEDB_241101,IEDB_983931,SB_192
Methods: 13C NMR, 1H NMR, HMQC, COSY, FT-IR
Comments, role: NMR temperature was not specified
NCBI Taxonomy refs (TaxIDs): 79798Reference(s) to other database(s): GTC:G26777BZ
Show glycosyltransferases
NMR conditions: in D2O
[as TSV]
13C NMR data:
Linkage Residue C1 C2 C3 C4 C5 C6
bDGlcp 103.2 73.2 75.8 69.7 75.1 69.0
1H NMR data: present in publication
|
13C NMR data:
| Linkage | Residue | C1 | C2 | C3 | C4 | C5 | C6 |
| | bDGlcp | 103.2 | 73.2 | 75.8 | 69.7 | 75.1 | 69.0 |
|
There is only one chemically distinct structure: