Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: leaf
NCBI PubMed ID: 10514319Publication DOI: 10.1021/np990080oJournal NLM ID: 7906882Publisher: American Society of Pharmacognosy
Correspondence: Pauli GF <pauli
uni-muenster.de>
Institutions: Department of Pharmaceutical Biology, University of Würzburg, Würzburg, Germany, Institute of Pharmaceutical Biology and Phytochemistry, Westfälische Wilhelms-University, Hittorfstrasse 56, D-48149 Münster, Germany
The three major flavonoids isolated from Arabidopsis thaliana plants grown in the greenhouse were identified by means of spectroscopic analysis (UV, NMR, MS) and chiral capillary zone electrophoresis as the novel kaempferol 3-O-β-[β-D-glucopyranosyl(1→6)D-glucopyranoside]-7-O-α-L-rhamnopyranoside (1), kaempferol 3-O-β-D-glucopyranoside-7-O-α-L-rhamnopyranoside (2), and kaempferol 3-O-α-L-rhamnopyranoside-7-O-α-L-rhamnopyranoside (3). Comprehensive NMR studies including selective 1D and gradient-enhanced 2D techniques were applied in order to achieve full signal assignment and definitive proof of linkage for compound 1.
flavonoid, Arabidopsis thaliana, flavone glycoside
Structure type: oligomer
Location inside paper: compound 2, kaempferol 3-O-β-D-glucopyranoside-7-O-α-L-rhamnopyranoside
Trivial name: f2
Compound class: glycoside, flavonoid glycoside, flavonol glycoside, flavone glycoside
Contained glycoepitopes: IEDB_136105,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 13C NMR, 1H NMR, IR, TLC, MALDI-TOF MS, HPLC, UV, capillary electrophoresis (CE), TOCSY, HMBC, COSY, HSQC, HRMS, TFA hydrolysis, reduction with NaCNBH3, API-MS
Comments, role: compound was identified based on comparison of UV, MS, and 1H and 13C NMR data with thereof in literature, see ref. [6-8]
Related record ID(s): 63333, 63335
NCBI Taxonomy refs (TaxIDs): 3702Reference(s) to other database(s): CCSD:
49908, CBank-STR:2587
Show glycosyltransferases
There is only one chemically distinct structure:
Found 
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(previously named: Arabis thaliana)