In the present study, the species: Beauveria bassiana, Absidia coerulea and Absidia glauca were used in biotransformation of flavones (chrysin, apigenin, luteolin, diosmetin) and flavanones (pinocembrin, naringenin, eriodictyol, hesperetin). The Beauveria bassiana AM 278 strain catalyzed the methylglucose attachment reactions to the flavonoid molecule at positions C7 and C3'. The application of the Absidia genus (A. coerulea AM 93, A. glauca AM 177) as the biocatalyst resulted in the formation of glucosides with a sugar molecule present at C7 and C3' positions of flavonoids skeleton. Nine of obtained products have not been previously reported in the literature.
- Compound ID: 18499
|
b-D-Glcp4Me-(1-7)-Subst
Subst = chrysin = SMILES O=C1C=C(OC2=C1{5}C(O)=C{7}C(O)=C2)C3=CC=CC=C3 |
Show graphically |
Structure type: monomer
C22H22O9
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21970
Structure type: monomer
; 445.1138 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21971
|
b-D-Glcp4Me-(1-7)-Subst
Subst = luteolin = SMILES C1=C{54}C(={53}C(C=C1C2=CC(=O)C3={5}C({6}C={7}C({8}C=C3O2)O)O)O)O |
Show graphically |
Structure type: monomer
; 461.1087 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21972
|
b-D-Glcp4Me-(1-7)-Subst4'Me
Subst = luteolin = SMILES C1=C{54}C(={53}C(C=C1C2=CC(=O)C3={5}C({6}C={7}C({8}C=C3O2)O)O)O)O |
Show graphically |
Structure type: monomer
; 475.1234 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21973
|
b-D-Glcp4Me-(1-3')-Subst4'Me
Subst = luteolin = SMILES C1=C{54}C(={53}C(C=C1C2=CC(=O)C3={5}C({6}C={7}C({8}C=C3O2)O)O)O)O |
Show graphically |
Structure type: monomer
; 475.1234 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21974
|
b-D-Glcp4Me-(1-7)-Subst
Subst = pinocembrin = SMILES O=C1CC(OC2=C1{5}C(O)=C{7}C(O)=C2)C3=CC=CC=C3 |
Show graphically |
Structure type: monomer
; 431.1345 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21975
|
b-D-Glcp4Me-(1-7)-Subst
Subst = naringenin = SMILES O=C1CC(C2=CC={54}C(O)C=C2)OC3=C{7}C(O)={6}C{5}C(O)=C13 |
Show graphically |
Structure type: monomer
; 447.1292 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21976
|
b-D-Glcp4Me-(1-7)-Subst
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
; 463.1245 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21977
|
b-D-Glcp4Me-(1-7)-Subst4'Me
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
; 477.1401 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21978
|
b-D-Glcp4Me-(1-3')-Subst4'Me
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
; 477.1401 [M-H]-
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21986
|
b-D-Glcp-(1-3')-Subst4'Me
Subst = luteolin = SMILES C1=C{54}C(={53}C(C=C1C2=CC(=O)C3={5}C({6}C={7}C({8}C=C3O2)O)O)O)O |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21410
|
b-D-Glcp-(1-7)-Subst
Subst = naringenin = SMILES O=C1CC(C2=CC={54}C(O)C=C2)OC3=C{7}C(O)={6}C{5}C(O)=C13 |
Show graphically |
Structure type: monomer
Trivial name: prunin
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21981
|
b-D-Glcp-(1-7)-Subst
Subst = chrysin = SMILES O=C1C=C(OC2=C1{5}C(O)=C{7}C(O)=C2)C3=CC=CC=C3 |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21982
Structure type: monomer
Trivial name: cosmosiin, apigenin 7-O-glucoside, rhoifolin, apigenin 7-glucoside, apigetrin
Compound class: glycoside, flavonoid glycoside, flavonol glycoside
Reference(s) to other database(s): CCSD:
50502, CBank-STR:1305
- Compound ID: 21983
|
b-D-Glcp-(1-7)-Subst
Subst = pinocembrin = SMILES O=C1CC(OC2=C1{5}C(O)=C{7}C(O)=C2)C3=CC=CC=C3 |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21984
|
b-D-Glcp-(1-7)-Subst4'Me
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21985
|
b-D-Glcp-(1-3')-Subst4'Me
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21979
|
b-D-Glcp-(1-3')-Subst
Subst = luteolin = SMILES C1=C{54}C(={53}C(C=C1C2=CC(=O)C3={5}C({6}C={7}C({8}C=C3O2)O)O)O)O |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside
- Compound ID: 21980
|
b-D-Glcp-(1-7)-Subst
Subst = eriodictyol = SMILES O=C1C[C@H](OC2=C1{5}C(O)=C{7}C(O)=C2)C3=C{53}C(O)={54}C(O)C=C3 |
Show graphically |
Structure type: monomer
Compound class: glycoside, flavonoid glycoside