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1. (Article ID: 9765)
Tomoda M, Suzuki Y, Satoh N
Plant mucilages. XXIII. Partial hydrolysis of Abelmoschus mucilage M and the structural features of its polysaccharide moiety
Chemical and Pharmaceutical Bulletin 27(7) (1979)
1651-1656
Partial acid hydrolysis of Abelmoschus-mucilage M, a representative mucilage isolated from the roots of Abelmoschus manihot MEDICUS, led to the isolation of three oligosaccharides. Analysis of components, reduction and methylation, and partial degradation studies showed that these oligosaccharides are O-α-(D-galactopyranosyluronic acid)-(1→2)-L-rhamnopyranose, O-β-(D-glucopyranosyluronic acid)-(1→3)-O-α-(D-galactopyranosyluronic acid)-(1→2)-L-rhamnopyranose, and O-β-(D-glucopyranosyluronic acid)-(1→3)-O-α-(D-galactopyranosyluronic acid)-(1→2)-O-α-L-rhamnopyranosyl-(1→4)-[O-β-(D-glucopyranosyluronic acid)-(1→3)]-O-α-(D-galactopyranosyluronic acid)-(1→2)-L-rhamnopyranose. The structural features of the polysaccharide moiety in the mucilage are discussed.
partial acid hydrolysis, reduction and methylation analysis, Abelmoschus manihot, Abelmoschus-mucilage M, isolation of three oligosaccharides, proton magnetic resonance, structures of three oligosaccharides, structural feature of polysaccharide moiety
Journal NLM ID: 0377775WWW link: http://ci.nii.ac.jp/naid/110003623705Publisher: Pharmaceutical Society Of Japan
Institutions: Kyoritsu College of Pharmacy, Tokyo, Japan
Methods: GLC-MS, IR, partial acid hydrolysis, TLC, GLC, methylation analysis, paper electrophoresis, PPC, PMR, reduction analysis
The publication contains the following compound(s):
- Compound ID: 23781
Structure type: oligomer
Reference(s) to other database(s): GTC:G74520OQ, CCSD:
10348, CBank-STR:4916
- Compound ID: 23782
|
b-D-GlcpA-(1-3)-+
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b-D-GlcpA-(1-3)-a-D-GalpA-(1-2)-a-L-Rhap-(1-4)-a-D-GalpA-(1-2)-L-Rha |
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Structure type: oligomer
Reference(s) to other database(s): GTC:G04557ZT, CCSD:
19523, CBank-STR:13849
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2. (Article ID: 10039)
Shimizu N, Tomoda M
Carbon-13 nuclear magnetic resonance spectra of alditol-form oligosaccharides having the fundamental structural units of the Malvaceae plant mucilages and a related polysaccharide
Chemical and Pharmaceutical Bulletin 33 (1985)
5539-5542
The carbon-13 nuclear magnetic resonance spectra of five alditol-form oligosaccharides and a polysaccharide having the fundamental structural units of the Malvaceae plant mucilages were measured in aqueous solution and the signals were assigned.
13C NMR, structural unit, Malvaceae, plant mucilage, alditol-form oligosaccharide
Journal NLM ID: 0377775WWW link: http://ci.nii.ac.jp/naid/110003625376Publisher: Pharmaceutical Society Of Japan
Institutions: Kyoritsu College of Pharmacy, Tokyo, Japan
Methods: 13C NMR, gel filtration, acid hydrolysis, NaBH4 reduction
The publication contains the following compound(s):
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3. (Article ID: 10706)
Stephen AM
Plant polysaccharides-how regular are they?
South African Journal of Chemistry = Suid-Afrikaanse Tydskrif Vir Chemie 40 (1987)
89-99
Journal NLM ID: 100954998Publisher: Foundation for Education, Science and Technology
The publication contains the following compound(s):
- Compound ID: 26581
Structure type: polymer chemical repeating unit
Reference(s) to other database(s): GTC:G50950IC, CCSD:
400, CBank-STR:7369
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4. (Article ID: 11477)
Perez GRM, Zavala SMA, Perez GS, Perez GC
Antidiabetic effect of compounds isolated from plants
Phytomedicine 5(1) (1998)
55-75
This review shows some of the compounds isolated and identified from the plants that previously demostrated a hypoglycemic effect. These compounds have been classified in appropiate chemical groups and data are reported on their pharmacological activity, mechanism of action, and other properties. This paper reviews mucilages, glycans, proteins, pectins, flavonoids, steroids and triterpenoids, alkaloids, other nitrogen compounds and miscellaneous substances with hypoglycemic effect.
proteins, chemical structures, Plants, glycans, pectins, steroids, triterpenoids, flavonoids, hypoglycemic compounds, mucilages, alkaloids and other nitrogen compounds
NCBI PubMed ID: 23195700Publication DOI: 10.1016/S0944-7113(98)80060-3Journal NLM ID: 9438794Publisher: Stuttgart: Urban & Fischer Verlag
Institutions: Laboratorio de Investigation de Productos Naturales, Escuela Superior de Ingenieria Quimica e Industrias Extractivas, Mexico, Mexico, Departamento de Sistemas Biologicos Universidad Autonoma Metropolitana-Xochimilco, Mexico, Mexico
The publication contains the following compound(s):
- Compound ID: 29314
Structure type: fragment of a bigger structure
Trivial name: mucilage
- Compound ID: 29318
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/Variants 0/-b-D-Glcp
/Variants 0/ is:
Subst2-(3-1)-
OR (exclusively)
Subst1-(3-1)-
Subst1 = β-sitosterol = SMILES O{3}[C@H](C1)CC[C@@]2(C)C1=CC[C@]3([H])[C@@]2([H])CC[C@@]4(C)[C@]3([H])CC[C@]4([C@@H](C)CC[C@@H](CC)C(C)C)[H];
Subst2 = 5,25-stigmastadienol = SMILES C=C(C)[C@@H](CC[C@H](C)C3CCC4C2C/C=C\1C{3}[C@@H](O)CC[C@]1(C)C2CC[C@]34C)C(C)C |
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Structure type: monomer
Trivial name: sitosterol-D-glucoside, 5,25-stigmastadienol-glucoside
Compound class: glycoside
- Compound ID: 29319
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b-D-Glcp-(1-5)-Subst
Subst = divicine = SMILES Nc1nc(N){5}c(O)c(=O)[nH]1 |
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Structure type: monomer
Trivial name: vicine
Compound class: glycoside
- Compound ID: 29321
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a-L-Rhap-(1-4)-a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Subst
Subst = (Z)-3-methyl-dodeca-1,10-dien = SMILES C=C{3}C(C)(O)CCCCCC/C=C\C |
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Structure type: oligomer
Compound class: glycoside
- Compound ID: 29315
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/Variants 0/-Rhap
/Variants 0/ is:
Quercetin-(3-1)-
OR (exclusively)
Kaempferol-(3-1)- |
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Structure type: monomer
Trivial name: quercetin-3-O-rhamnoside, kaempferol-3-O-rhamnoside
Compound class: glycoside
- Compound ID: 29317
Structure type: oligomer
Trivial name: ginsenoside Rg2
Compound class: triterpenoid glycoside
- Compound ID: 29320
Structure type: oligomer
Trivial name: coyolose
Compound class: glycoside
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