Novel triterpenoid saponins, dianosides A and B, showing analgesic activity, have been isolated from DIANTHUS SUPERBUS var. LONGICALYCINUS herbs. Degradative and spectroscopic studies have established their structures as shown in formulas 1 and 2.

• Compound ID: 25456
  

  b-D-Glcp-(1-3)-+ | b-D-Glcp-(1-6)-+ | | | b-D-Glcp-(1-3)-b-D-Glcp-(1-28)-Subst Subst = gypsogenic acid = SMILES C[C@]12CC{3}[C@H](O)[C@@](C)({23}C(O)=O)[C@@H]1CC[C@]3(C)[C@@H]2CC=C4[C@@]3(C)CC[C@]5({28}C(O)=O)[C@H]4CC(C)(C)CC5

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  Structure type: oligomer
  Trivial name: dianoside B
  Compound class: saponin glycoside
  Reference(s) to other database(s): CCSD:28079, CBank-STR:10515
  
   
  
  Dianthus superbus var. longicalycinus
  CSDB ID 147200 (all data & tools)
• Compound ID: 25457
  

  b-D-Glcp-(1-3)-+ | b-D-Glcp-(1-28)-Subst Subst = gypsogenic acid = SMILES C[C@]12CC{3}[C@H](O)[C@@](C)({23}C(O)=O)[C@@H]1CC[C@]3(C)[C@@H]2CC=C4[C@@]3(C)CC[C@]5({28}C(O)=O)[C@H]4CC(C)(C)CC5

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  Show legend Show as text

  Structure type: oligomer
  Trivial name: dianoside A
  Compound class: saponin glycoside
  Reference(s) to other database(s): CCSD:28080, CBank-STR:2945
  
   
  
  Dianthus superbus var. longicalycinus
  CSDB ID 147199 (all data & tools)