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1. (Article ID: 10573)
Moon JH, Watanabe N, Sakata K, Yagi A, Ina K, Luo S
trans- and cis-linalool 3,6-oxide 6-O-β-D-xylopyranosyl-β-D-glucopyranosides isolated as aroma precursors from leaves for oolong tea
Bioscience, Biotechnology, and Biochemistry 58 (1994)
1742-1744
New glycosidic aroma precursors (1 and 2) of the main volatile constituents, trans- and cis-linalool 3,6-oxides (linalool oxides I and II), were isolated from oolong tea leaves (Camellia sinensis var. sinensis cv. Maoxie). The isolation was guided by an enzymatic hydrolysis with acetone powder prepared from fresh tea leaves (cv. Yabukita) followed by GC or GC-MS analyses. Chromatographic purification of hot water extracts of the tea leaves on active charcoal, Amberlite XAD-2, and Sephadex LH-20 columns as well as HPLC gave two new glycosides, trans- and cis-linalool 3,6-oxide 6-O-β-D-xylopyranosyl-β-D-glucopyranosides (1 and 2).
NCBI PubMed ID: 7765491Publication DOI: 10.1271/bbb.58.1742Journal NLM ID: 9205717Publisher: Japan Society for Bioscience, Biotechnology, and Agrochemistry
Institutions: Department of Applied Biological Chemistry, Faculty of Agriculture, Shizuoka University, Japan
The publication contains the following compound(s):
- Compound ID: 24313
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b-D-Xylp-(1-6)-b-D-Glcp-(1-7)-Subst
Subst = trans-linalool-3,6-oxide = SMILES C[C@]1(CC[C@H](O1){7}C(C)(C)O)C=C |
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Structure type: oligomer
C21H36O11
Trivial name: 8-hydroxygeranyl β-primeveroside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
34653, CBank-STR:4033
- Compound ID: 24314
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b-D-Xylp-(1-6)-b-D-Glcp-(1-7)-Subst
Subst = cis-linalool-3,6-oxide = SMILES C{7}C(C)(O)[C@H]1CC[C@](C)(O1)C=C |
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Structure type: oligomer
C21H36O11
Trivial name: 8-hydroxygeranyl β-primeveroside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
34654, CBank-STR:4031
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2. (Article ID: 10798)
Ikeda Y, Fujii Y, Nakaya I, Yamazaki M
Quantitative HPLC analysis of cardiac glycosides in Digitalis purpurea leaves
Journal of Natural Products 58 (1995)
897-901
An analytical method for the determination of cardiac glycosides in Digitalis purpurea leaves by hplc was developed. Quantitation was carried out by the incorporation of lanatoside A as an internal standard. The present method is sufficiently precise and relatively simple.
NCBI PubMed ID: 7673934Journal NLM ID: 7906882Publisher: American Society of Pharmacognosy
Institutions: Faculty of Pharmaceutical Sciences, Hokuriku University, Kanazawa, Japan
The publication contains the following compound(s):
- Compound ID: 25275
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b-D-Digp-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = digitoxigenin = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])CC[C@]4(C)[C@@H](C(CO5)=CC5=O)CC{14}[C@]4(O)[C@]3([H])CC[C@@]([H])2C1 |
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Structure type: oligomer
Trivial name: digitoxin
Compound class: saponin glycoside, glycoside, triterpenoid glycoside, cardiac glycoside
Reference(s) to other database(s): CCSD:
43339, CBank-STR:3858
- Compound ID: 26877
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b-D-Digp-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = gitoxigenin = SMILES O=C1OCC([C@H]2{16}[C@@H](O)C{14}[C@]3(O)[C@]4([H])CC[C@]5([H])C{3}[C@@H](O)CC[C@]5(C)[C@@]4([H])CC[C@]23C)=C1 |
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Structure type: oligomer
Trivial name: gitoxin
Compound class: saponin glycoside, glycoside, cardiac glycoside
Reference(s) to other database(s): CCSD:
43340, CBank-STR:3857
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