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1. (Article ID: 10895)
Schopke T, Thiele H, Wray V, Nimtz M, Hiller K
Structure elucidation of a glycoside of 2β,3β-23-trihydroxy-16-oxoolean-12-en-28-oic acid from Bellis bernardii using mass spectrometry for the sugar sequence determination
Journal of Natural Products 58 (1995)
152-155
The structure of a novel saponin, possessing an unusual aglycone named bellisonic acid and isolated from whole plants of Bellis bernardii, has been elucidated by modern ms and nmr techniques as 3-O-α-L-rhamnopyranosyl-2β,3β,23-trihydroxy-16-oxoolean-12-en-28-oic acid 28-α-L-rhamnopyranosyl(1→3)-O-β-D-xylopyranosyl(1→4)-α-L- rhamnopyranosyl(1→2)-β-D-fucopyranoside [1]. Ms procedures of general applicability allowed unambiguous sugar sequence determination from very small amounts of material.
NCBI PubMed ID: 7760074Journal NLM ID: 7906882Publisher: American Society of Pharmacognosy
Institutions: Humboldt-Universität zu Berlin, Fachbereich Pharmazie, Germany
The publication contains the following compound(s):
- Compound ID: 27113
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a-L-Rhap-(1-3)-+
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a-L-Rhap-(1-3)-b-D-Xylp-(1-4)-a-L-Rhap-(1-2)-b-D-Fucp-(1-28)-Subst
Subst = 16-oxo-olean-12-en-2β,3β,23-triol-28-oic acid = SMILES C[C@]({23}CO)([C@](CC[C@@]([C@](C1)2C)3C)4[H]){3}[C@@H](O){2}[C@@H](O)C[C@]4(C)[C@@]3([H])CC=C2[C@]5([H])CC(C)(C)CC[C@@]({28}C(O)=O)5C1=O |
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Structure type: oligomer
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
48882, CBank-STR:12452
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