In addition to solamargine, two new steroid alkaloid glycosides, anguivine and isoanguivine, have been isolated from the roots of Solanum anguivi, the structures of which have been elucidated as (25R)-3-β-[O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-xylopyranosyl-(1→3)]-β-D-glucopyranosyloxy]-22α-N-spirosol-5-ene and (25R)-3-β-[O-α-L-rhamnopyranosyl-(1→2)-O-[β-D-xylopyranosyl-(1→3)-β-D-galactopyranosyloxy]-22α-N-spirosol-5-ene.

• Compound ID: 27234
  

  b-D-Xylp-(1-3)-+ | a-L-Rhap-(1-2)-b-D-Glcp-(1-3)-Subst Subst = 22β-solasodine = SMILES [H][C@]1(O[C@]2(NC[C@H](C)CC2)[C@H]3C)C[C@@]4([H])[C@]5([H])CC=C6C{3}[C@@H](O)CC[C@]6(C)[C@@]5([H])CC[C@]4(C)[C@]13[H]

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  Structure type: oligomer
  Trivial name: anguivine
  Compound class: saponin glycoside, glycoside
  Reference(s) to other database(s): CCSD:49875, CBank-STR:6947
  
   
  
  Solanum anguivi
  CSDB ID 146583 (all data & tools)
• Compound ID: 27235
  

  b-D-Xylp-(1-3)-+ | a-L-Rhap-(1-2)-b-D-Galp-(1-3)-Subst Subst = 22β-solasodine = SMILES [H][C@]1(O[C@]2(NC[C@H](C)CC2)[C@H]3C)C[C@@]4([H])[C@]5([H])CC=C6C{3}[C@@H](O)CC[C@]6(C)[C@@]5([H])CC[C@]4(C)[C@]13[H]

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  Structure type: oligomer
  Trivial name: isoanguivine
  Compound class: saponin glycoside, glycoside
  Reference(s) to other database(s): CCSD:49876, CBank-STR:8708
  
   
  
  Solanum anguivi
  CSDB ID 146584 (all data & tools)