Adinolfi M, Corsaro MM, De Castro C, Evidente A, Lanzetta R, Molinaro A, Parrilli M Caryose: a carbocyclic monosaccharide from Burkholderia_Pseudomonas caryophylli Carbohydrate Research284 (1996)
111-118
The structure was elucidated in this paper Publication DOI:10.1016/0008-6215(96)00018-3 Journal NLM ID:0043535 Publisher: Elsevier Institutions: Dipartimento di Chimica Organica e Biologica, Universita di Napoli Federico II, via Mezzocannone 16, 801 34 Naples, Italy, Dipartimento di Science Chimico-Agrarie, Umuersita di Napoli Federico II, via Universita 100, 80055 Portici, Italy
The complete structure of the first example of a carbocyclic monosaccharide, named caryose (4,8-cyclo-3,9-dideoxy-L-erythro-D-ido-nonose) and obtained from the lipopolysaccharide fraction of Burkholderia_Pseudomonas caryophylli, is reported. The structure and the relative stereochemistry were inferred by chemical and spectroscopic analysis, and the absolute configuration was elucidated by the Exciton Chiral Coupling method.
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(previously named: Pseudomonas caryophylli NCPPB 2151, Paraburkholderia caryophylli NCPPB 2151; later renamed to: Trinickia caryophylli NCPPB 2151)