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1. (Article ID: 11341)
Ebringerova A, Srokova I, Talaba P, Kačuráková M, Hromádková Z
Amphiphilic beechwood glucuronoxylan derivatives
Journal of Applied Polymer Science 97(9) (1998)
1523-1530
Long alkyl chains (C-12) have been introduced onto glucuronoxylan and its sulfoethyl derivative via O-alkylation using 1-bromododecane in dimethylsulfoxide. The new amphiphilic xylan derivatives were characterized by chemical, elemental, and spectral analyses. They reduce the surface tension and exhibit remarkable emulsifying and protein foam-stabilizing properties. The results indicate that the development of new biopolymeric surfactants may be based on heteroxylans that are abundant in hardwoods and annual plants, and represent an unexploited renewable polysaccharide resource.
structure, surface tension, beechwood glucuronoxylan, amphiphilic derivative, foamability, emulsifying efficiency
Publication DOI: 10.1002/(SICI)1097-4628(19980228)67:9<1523::AID-APP3>3.0.CO;2-FJournal NLM ID: 9891577Publisher: Wiley
Institutions: Institute of Chemistry, Slovak Academy of Sciences, Bratislava, Slovak Republic, Department of Fibres and Textile, Faculty of Chemical Technology, Slovak Technical University, Bratislava, Slovak Republic
Methods: 13C NMR, 1H NMR, elemental analysis, HPGPC, DEPT, determination of surface tension, FT-IR, titration
The publication contains the following compound(s):
- Compound ID: 28759
|
a-D-GlcpA4Me-(1-2)-+
|
-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1- |
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Structure type: polymer chemical repeating unit
; 32500
Compound class: glucuronoxylan
- Compound ID: 28760
|
S-2)-Subst-(1-2)-+
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a-D-GlcpA4Me-(1-2)-+ |
| |
-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-
|
S-2)-Subst-(1-3)-+
Subst = O{1}C{2}CO |
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Structure type: polymer chemical repeating unit
; 30000
Compound class: glucuronoxylan
- Compound ID: 28761
|
a-D-GlcpA4Me-(1-2)-+
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Subst1-(1-2)-+ |
| |
-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-
|
Subst1-(1-3)-+
Subst1 = SMILES CCCCCCCCCCC{1}CO |
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Structure type: polymer chemical repeating unit
; 29500
Compound class: glucuronoxylan
- Compound ID: 28762
|
S-2)-Subst1-(1-2)-+
|
a-D-GlcpA4Me-(1-2)-+ |
| |
Subst2-(1-2)-+ | |
| | |
-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-4)-b-D-Xylp-(1-
| |
Subst2-(1-3)-+ S-2)-Subst1-(1-3)-+
Subst1 = SILES O{1}C{2}CO;
Subst2 = SMILES CCCCCCCCCCC{1}CO |
Show graphically |
Structure type: polymer chemical repeating unit
; 31800
Compound class: glucuronoxylan
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