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1. (Article ID: 11424)
Nielsen JK, Norbaek R, Olsen CE
Kaempferol tetraglucosides from cabbage leaves
Phytochemistry 49(7) (1998)
2171-2176
Four flavonol glycosides were isolated from a leaf extract of cabbage and characterized by chemical and spectroscopic methods including H-1 and C-13 NR IR and negative ton FAB-MS. The common structure of the four compounds was kaempferol-3-O-beta-D-[beta-D-glucopyranosyl(1 --> 2)glucopyranoside]-7-O-beta-D-[beta-D-glucopyranosyl(1 --> 4) glucopyranoside]. This compound was found unmodified or acylated at C-2''' (outer glucose in sophorosyl moiety) with either sinapic acid, ferulic acid or caffeic acid. The possible role of diversity in glycosylation and acylation patterns of flavonol glycosides for plant defences against herbivores is discussed.
acylated, flavonol glycosides, Brassica oleracea, Cruciferae, cabbage, caffeoyl, feruloyl, sinapoyl
NCBI PubMed ID: 9883597Publication DOI: 10.1016/s0031-9422(98)00422-1Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Chemistry Department, Royal Veterinary and Agricultural University, Frederiksberg C, Denmark
Methods: 13C NMR, 1H NMR, NOE, FAB-MS, paper chromatography, UV, extraction, CC, HMBC, COSY, HOHAHA, HSQC
The publication contains the following compound(s):
- Compound ID: 29091
|
b-D-Glcp-(1-7)-+
|
/Variants 0/-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol
/Variants 0/ is:
?%Fer-(9-2)-
OR (exclusively)
?%Caf-(9-2)- |
Show graphically |
Structure type: oligomer
Compound class: glycoside
- Compound ID: 29092
|
b-D-Glcp-(1-7)-+
|
Sin-(9-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol |
Show graphically |
Structure type: oligomer
Compound class: glycoside
- Compound ID: 29093
|
b-D-Glcp-(1-4)-b-D-Glcp-(1-7)-+
|
b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol |
Show graphically |
Structure type: oligomer
Compound class: glycoside
- Compound ID: 29094
|
b-D-Glcp-(1-4)-b-D-Glcp-(1-7)-+
|
Sin-(9-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol |
Show graphically |
Structure type: oligomer
Compound class: glycoside
- Compound ID: 29095
|
b-D-Glcp-(1-4)-b-D-Glcp-(1-7)-+
|
Fer-(9-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol |
Show graphically |
Structure type: oligomer
Compound class: glycoside
- Compound ID: 29096
|
b-D-Glcp-(1-4)-b-D-Glcp-(1-7)-+
|
Caf-(9-2)-b-D-Glcp-(1-2)-b-D-Glcp-(1-3)-Kaempferol |
Show graphically |
Structure type: oligomer
Compound class: glycoside
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