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1. (Article ID: 11543)
De Castro D, Gomes F, Alegrio L
Acyl steryl glycosides from Pithecellobium cauliflorum
Phytochemistry 49(5) (1998)
1365-1367
One sterolglycoside and two sterolglycolipids, were found in the branches of Pithecellobium cauliflorum (Willd.) Mart., namely the β-D- glucoside of α-spinasterol (glucosylsterol, minor component), 3-O-[6'-O- palmitoyl-β-D-glucosyl]-spinasta-7, 22(23)-diene, and 3-O-[6'-O-stearoyl- β-D-glucosyl]-spinasta-7, 22(23)-diene (acylglucosylsterols, major components). Each was isolated and identified by a combination of different chromatographic, hydrolytic and spectroscopic methods, respectively.
Leguminosae, acyl steryl glycosides, Pithecellobium cauliflorum
Publication DOI: 10.1016/S0031-9422(97)00925-4Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Departamento de Química-Instituto de Ciências Exatas, Universidade Federal Rural do Rio de Janeiro, Seropédica, Brazil
Methods: 13C NMR, 1H NMR, IR, TLC, extraction, CC, melting point determination, DEPT, COSY, CTLC
The publication contains the following compound(s):
- Compound ID: 29609
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b-D-Glcp-(1-3)-Subst
Subst = spinasta-7,22-diene = SMILES CC(C)[C@H](C)/C=C/C(C)C4CCC3/C2=C/CC1C{3}[C@@H](O)CC[C@]1(C)C2CC[C@@]34C |
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Structure type: monomer
Compound class: triterpenoid glycoside
- Compound ID: 29610
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b-D-Glcp2Ac3Ac4Ac6Ac-(1-3)-Subst
Subst = spinasta-7,22-diene = SMILES CC(C)[C@H](C)/C=C/C(C)C4CCC3/C2=C/CC1C{3}[C@@H](O)CC[C@]1(C)C2CC[C@@]34C |
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Structure type: monomer
Compound class: triterpenoid glycoside
- Compound ID: 29611
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Pam-(1-6)-b-D-Glcp-(1-3)-Subst
Subst = spinasta-7,22-diene = SMILES CC(C)[C@H](C)/C=C/C(C)C4CCC3/C2=C/CC1C{3}[C@@H](O)CC[C@]1(C)C2CC[C@@]34C |
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Structure type: monomer
Compound class: triterpenoid glycoside
- Compound ID: 29612
|
Ste-(1-6)-b-D-Glcp-(1-3)-Subst
Subst = spinasta-7,22-diene = SMILES CC(C)[C@H](C)/C=C/C(C)C4CCC3/C2=C/CC1C{3}[C@@H](O)CC[C@]1(C)C2CC[C@@]34C |
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Structure type: monomer
Compound class: triterpenoid glycoside
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