Phytochemical study of the leaves and stems of Jasminum nudiflorum has led to the isolation of three secoiridoid glucosides, jasnudiflosides A-C (1-3). The structures of these compounds were elucidated on the basis of chemical and spectroscopic evidence.

Jasminum nudiflorum, jasnudifloside A, jasnudifloside B, jasnudifloside C, secoiridoid glucoside

• Compound ID: 30741
  

  b-D-Glcp-(1-1)-+ | b-D-Glcp-(1-1)-Subst1-11Me-(7-7)-Subst2-(5-7)-Subst1-11Me Subst1 = oleoside aglycon = SMILES C/C=C\1{1}[C@H](O)O/C=C({11}C(=O)O)\[C@H]1C{7}C(=O)O; Subst2 = (1S,2R,3S,4S)-3-(hydroxymethyl)-4-[(2R)-1-hydroxy-2-propanyl]-2-methylcyclopentanol = SMILES [H][C@](C)({10}CO)[C@@H]1C{5}[C@H](O)[C@H](C)[C@H]1{7}CO

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  Structure type: oligomer ; 959 [M-H]-
  C44H64O23
  Trivial name: jasnudifloside A
  Compound class: iridoid glycoside
  
   
  
  Jasminum nudiflorum
  CSDB ID 63342 (all data & tools)
• Compound ID: 30742
  

  b-D-Glcp2Ac3Ac4Ac6Ac-(1-1)-+ | b-D-Glcp2Ac3Ac4Ac6Ac-(1-1)-Subst1-11Me-(7-7)-Subst2-10Ac-(5-7)-Subst1-11Me Subst1 = oleoside aglycon = SMILES C/C=C\1{1}[C@H](O)O/C=C({11}C(=O)O)\[C@H]1C{7}C(=O)O; Subst2 = (1S,2R,3S,4S)-3-(hydroxymethyl)-4-[(2R)-1-hydroxy-2-propanyl]-2-methylcyclopentanol = SMILES [H][C@](C)({10}CO)[C@@H]1C{5}[C@H](O)[C@H](C)[C@H]1{7}CO

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  Structure type: oligomer ; 1361.4722 [M+Na]+
  C62H82O32
  Compound class: iridoid glycoside
  
   
  
  Jasminum nudiflorum
  CSDB ID 63343 (all data & tools)
• Compound ID: 30743
  

  b-D-Glcp-(1-1)-+ | b-D-Glcp-(1-1)-Subst1-11Me-(7-7)-Subst2-(5-7:10-11)-Subst1 Subst1 = oleoside aglycon = SMILES C/C=C\1{1}[C@H](O)O/C=C({11}C(=O)O)\[C@H]1C{7}C(=O)O; Subst2 = (1S,2R,3S,4S)-3-(hydroxymethyl)-4-[(2R)-1-hydroxy-2-propanyl]-2-methylcyclopentanol = SMILES [H][C@](C)({10}CO)[C@@H]1C{5}[C@H](O)[C@H](C)[C@H]1{7}CO

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  Structure type: oligomer ; 927 [M-H]-
  C43H60O22
  Trivial name: jasnudifloside C
  Compound class: iridoid glycoside
  
   
  
  Jasminum nudiflorum
  CSDB ID 63344 (all data & tools)
• Compound ID: 30744
  

  b-D-Glcp-(1-1)-+ | b-D-Glcp-(1-1)-Subst1-11Me-(7-7)-+ | | | b-D-Glcp-(1-1)-Subst1-11Me-(7-10)-Subst2-(5-7)-Subst1-11Me Subst1 = oleoside aglycon = SMILES C/C=C\1{1}[C@H](O)O/C=C({11}C(=O)O)\[C@H]1C{7}C(=O)O; Subst2 = (1S,2R,3S,4S)-3-(hydroxymethyl)-4-[(2R)-1-hydroxy-2-propanyl]-2-methylcyclopentanol = SMILES [H][C@](C)({10}CO)[C@@H]1C{5}[C@H](O)[C@H](C)[C@H]1{7}CO

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  Structure type: oligomer ; 1345 [M-H]-
  C61H86O33
  Trivial name: jasnudifloside B
  Compound class: iridoid glycoside
  
   
  
  Jasminum nudiflorum
  CSDB ID 63345 (all data & tools)