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1. (Article ID: 12145)
Du X-M, Sun N-Y, Irino N, Shoyama Y
Glycosidic constituents from in vitro Anoectochilus formosanus
Chemical and Pharmaceutical Bulletin 48(11) (2000)
1803-1804
The glycosidic constituents of whole plants of Anoectochilus formosanus propagated by tissue culture were investigated. A new compound, 2-(β-D-glucopyranosyloxymethyl)-5-hydroxymethylfuran, along with the known compounds, 3-(R)-3-β-D-glucopyranosyloxybutanolide (kinsenoside), 3-(R)-3-β-D-glucopyranosyloxy-4-hydroxybutanoic acid, 1-O-isopropyl-β-D-glucopyranoside, (R)-(+)-3,4-dihydroxy-butanoic acid y-lactone, 4-(β-D-glucopyranosyloxy)benzyl alcohol, (6R,9S)-9-hydroxy-megastigma-4,7-dien-3-one-9-O-β-D-glucopyranoside, and corchoionoside C were isolated.
glycoside, tissue culture, Anoectochilus formosanus
NCBI PubMed ID: 11086921Publication DOI: 10.1248/cpb.48.1803Journal NLM ID: 0377775Publisher: Pharmaceutical Society Of Japan
Correspondence: shoyama
shoyaku.phar.kyushu-u.ac.jp
Institutions: Graduate School of Pharmaceutical Sciences, Kyushu University, Fukuoka, Japan, Seiwa Pharmaceuticals Ltd., Tokyo, Japan
Methods: 13C NMR, 1H NMR, EI-MS, acid hydrolysis, GC, extraction, optical rotation measurement, CC, melting point determination, derivatization, PTLC, HR-EI-MS
The publication contains the following compound(s):
- Compound ID: 28196
|
b-D-Glcp-(1-9)-Subst
Subst = 6R,9S-3-oxo-α-ionol = SMILES O=C1CC(C)([C@H](C(C)=C1)/C=C/{9}[C@H](C)O)C |
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Structure type: monomer
Compound class: saponin glycoside, glycoside
- Compound ID: 28197
|
b-D-Glcp-(1-9)-Subst
Subst = (6S,9S)-vomifoliol = SMILES O=C1CC(C)({6}[C@@](C(C)=C1)(O)/C=C/{9}[C@H](C)O)C |
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Structure type: monomer
Trivial name: corchoionoside C, (6S,9S)-releoside, corchoinoside C
Compound class: saponin glycoside, glycoside, sesquiterpenoid glycoside
- Compound ID: 31567
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b-D-Glcp-(1-3)-Subst
Subst = (S)-4-hydroxydihydrofuran-2(3H)-one = SMILES O=C1C{3}[C@H](O)CO1 |
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Structure type: monomer
Compound class: glycoside
- Compound ID: 31568
Structure type: monomer
Compound class: glycoside
- Compound ID: 31569
Structure type: monomer
Compound class: glycoside
- Compound ID: 31570
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b-D-Glcp-(1-4)-Subst
Subst = 4-hydroxybenzyl alcohol = SMILES O{4}C1=CC=C({7}CO)C=C1 |
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Structure type: monomer
Compound class: glycoside
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