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1. (Article ID: 12844)
Yahara S, Kohjyouma M, Kohoda H
Flavonoid glycosides and saponins from Astragalus shikokianus
Phytochemistry 53(4) (2000)
469-471
A new flavonol glycoside, kaempferol 3-O-α-L-rhamnopyranosy1-(1 → 6)-[α-L-rhamnopyranosyl-(1 → 2)]-β-D-galactopyranosyl-7-O-α-L-rhamnopyranoside, named astrasikokioside I, was isolated from aerial part of Astragalus shikokianus, together with two flavonol glycosides, kaempferol 3-O-α-L-rhamnopyranosyl-(1 → 2)-β-D-galactopyranosyl-7-O-α-L-rhamnopyranoside, robinin, and three triterpenoid glycosides, soyasaponin I, sophoraflavoside II and robinioside E.
triterpenoid glycoside, flavonol glycoside, Leguminosae, robinin, clovin, soyasaponin I, sophoraflavoside, Astragalus shikokianus, astrasikokioside I, robinioside E
NCBI PubMed ID: 10731025Publication DOI: 10.1016/s0031-9422(99)00512-9Journal NLM ID: 0151434Publisher: Elsevier
Correspondence: yaharas1

gpo.kumamoto-u.ac.jp
Institutions: Faculty of Pharmaceutical Sciences, Kumamoto University, Kumamoto, Japan, Institute of Pharmaceutical Sciences, Hiroshima University School of Medicine, Hiroshima, Japan
Methods: 13C NMR, 1H NMR, NMR-2D, TLC, enzymatic hydrolysis, acid hydrolysis, HPLC, optical rotation measurement, HR-FAB-MS
The publication contains the following compound(s):
- Compound ID: 24277
Structure type: oligomer
Trivial name: robinin
Compound class: saponin glycoside, glycoside, flavonoid glycoside, flavonol glycoside, flavone glycoside
Reference(s) to other database(s): CCSD:
38864, CBank-STR:8363
- Compound ID: 24727
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a-L-Rhap-(1-2)-b-D-Galp-(1-2)-b-D-GlcpA6Me-(1-3)-SoyasapogenolB |
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Structure type: oligomer
Trivial name: soyasaponin I, dehydrosoyasaponin I, kaikasaponin
Compound class: saponin glycoside, glycoside, flavonoid glycoside
Reference(s) to other database(s): CCSD:
17896, CBank-STR:9580
- Compound ID: 25480
|
a-L-Rhap-(1-2)-b-D-Galp-(1-2)-b-D-GlcpA-(1-3)-Subst
Subst = oxytrogenin = SMILES C[C@]1({24}CO){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])C[C@](C)({29}C(O)=O)C{22}[C@@H](O)[C@@](C)5CC[C@](C)4[C@@](C)3CC[C@@]12[H] |
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Structure type: oligomer
Trivial name: sophoraflavoside II
Compound class: saponin glycoside, glycoside, flavonoid glycoside
Reference(s) to other database(s): CCSD:
28421, CBank-STR:9562
- Compound ID: 25567
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a-L-Rhap-(1-2)-b-D-Galp-(1-2)-b-D-GlcpA-(1-3)-Subst
Subst = abrisapogenol B = SMILES C[C@]1({24}CO){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])C[C@@]({29}CO)(C)C{22}[C@@H](O)[C@@](C)5CC[C@](C)4[C@@](C)3CC[C@@]12[H] |
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Structure type: oligomer
Trivial name: robinioside E
Compound class: saponin glycoside, glycoside
Reference(s) to other database(s): CCSD:
28768, CBank-STR:9565
- Compound ID: 32451
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a-L-Rhap-(1-7)-+
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a-L-Rhap-(1-6)-+ |
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a-L-Rhap-(1-2)-b-D-Galp-(1-3)-Kaempferol |
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Structure type: oligomer
Trivial name: desacylgladiatoside B, astrasikokioside I
Compound class: glycoside, flavonoid glycoside
- Compound ID: 33363
Structure type: oligomer
Compound class: glycoside, flavonoid glycoside
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