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Gaus HJ, Treumann A, Kreis W, Bayer E
Separation of cardiac glycosides by micellar electrokinetic capillary electrophoresis
Journal of Chromatography 635 (1993)
319-327
|
b-D-Digp3Me-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = digitoxigenin = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])CC[C@]4(C)[C@@H](C(CO5)=CC5=O)CC{14}[C@]4(O)[C@]3([H])CC[C@@]([H])2C1 |
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Digitalis lanata
(NCBI TaxID 49450,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Associated disease: infection due to Digitalis lanata [ICD11:
XM2SP4 
]
NCBI PubMed ID: 8486748Publication DOI: 10.1016/0021-9673(93)80375-IJournal NLM ID: 0427043Publisher: Amsterdam: Elsevier
Institutions: Institut für Organische Chemie, Universität Tübingen, Germany, Pharmazeutisches Institut, Universität Tübingen, Tübingen, Germany
The separation of mixtures of primary and secondary cardiac glycosides by micellar electrokinetic capillary electrophoresis modified by cyclodextrins, urea and sodium cholate proved to be suitable for the determination of these hydrophobic compounds. It was possible to distinguish the two anomeric cardenolides glucodigifucoside and glucodigiglucomethyloside with all three buffer systems. Electropherograms of crude plant cell extracts from Digitalis lanata were obtained with this method.
Structure type: oligomer
Trivial name: α-methyldigitoxin
Compound class: saponin glycoside
Methods: MIKE, micellar electrokinetic chromatography
NCBI Taxonomy refs (TaxIDs): 49450Reference(s) to other database(s): CCSD:
28920, CBank-STR:3881
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There is only one chemically distinct structure:
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Gaus HJ, Treumann A, Kreis W, Bayer E
Separation of cardiac glycosides by micellar electrokinetic capillary electrophoresis
Journal of Chromatography 635 (1993)
319-327
|
b-D-Digp3Me-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = 12β,16β-dihydroxydigitoxigenin = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])C{12}[C@@H](O)[C@]4(C)[C@@H](C(CO5)=CC5=O){16}[C@@H](O)C{14}[C@]4(O)[C@]3([H])CC[C@@]([H])2C1 |
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Digitalis lanata
(NCBI TaxID 49450,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Associated disease: infection due to Digitalis lanata [ICD11:
XM2SP4 ]
NCBI PubMed ID: 8486748Publication DOI: 10.1016/0021-9673(93)80375-IJournal NLM ID: 0427043Publisher: Amsterdam: Elsevier
Institutions: Institut für Organische Chemie, Universität Tübingen, Germany, Pharmazeutisches Institut, Universität Tübingen, Tübingen, Germany
The separation of mixtures of primary and secondary cardiac glycosides by micellar electrokinetic capillary electrophoresis modified by cyclodextrins, urea and sodium cholate proved to be suitable for the determination of these hydrophobic compounds. It was possible to distinguish the two anomeric cardenolides glucodigifucoside and glucodigiglucomethyloside with all three buffer systems. Electropherograms of crude plant cell extracts from Digitalis lanata were obtained with this method.
Structure type: oligomer
Location inside paper: Fig. 1, R2=R3=OH
Trivial name: β-methyldiginatin
Compound class: saponin glycoside
Methods: MIKE, micellar electrokinetic chromatography
NCBI Taxonomy refs (TaxIDs): 49450Reference(s) to other database(s): CCSD:
28919, CBank-STR:3886
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There is only one chemically distinct structure:
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Gaus HJ, Treumann A, Kreis W, Bayer E
Separation of cardiac glycosides by micellar electrokinetic capillary electrophoresis
Journal of Chromatography 635 (1993)
319-327
|
b-D-Glcp-(1-4)-b-D-Digp3Ac-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = digoxigenin = SMILES O=C1OCC([C@H]2CC{14}[C@]3(O)[C@]4([H])CC[C@]5([H])C{3}[C@@H](O)CC[C@]5(C)[C@@]4([H])C{12}[C@@H](O)[C@]23C)=C1 |
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Digitalis lanata
(NCBI TaxID 49450,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Associated disease: infection due to Digitalis lanata [ICD11:
XM2SP4 ]
NCBI PubMed ID: 8486748Publication DOI: 10.1016/0021-9673(93)80375-IJournal NLM ID: 0427043Publisher: Amsterdam: Elsevier
Institutions: Institut für Organische Chemie, Universität Tübingen, Germany, Pharmazeutisches Institut, Universität Tübingen, Tübingen, Germany
The separation of mixtures of primary and secondary cardiac glycosides by micellar electrokinetic capillary electrophoresis modified by cyclodextrins, urea and sodium cholate proved to be suitable for the determination of these hydrophobic compounds. It was possible to distinguish the two anomeric cardenolides glucodigifucoside and glucodigiglucomethyloside with all three buffer systems. Electropherograms of crude plant cell extracts from Digitalis lanata were obtained with this method.
Structure type: oligomer
Trivial name: lanatoside C
Compound class: saponin glycoside, glycoside, cardiac glycoside
Contained glycoepitopes: IEDB_142488,IEDB_146664,IEDB_983931,SB_192
Methods: MIKE, micellar electrokinetic chromatography
NCBI Taxonomy refs (TaxIDs): 49450Reference(s) to other database(s): CCSD:
45696, CBank-STR:8793
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There is only one chemically distinct structure:
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Gaus HJ, Treumann A, Kreis W, Bayer E
Separation of cardiac glycosides by micellar electrokinetic capillary electrophoresis
Journal of Chromatography 635 (1993)
319-327
|
b-D-Glcp-(1-4)-b-D-Digp3Ac-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = digitoxigenin = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])CC[C@]4(C)[C@@H](C(CO5)=CC5=O)CC{14}[C@]4(O)[C@]3([H])CC[C@@]([H])2C1 |
Show graphically |
Digitalis lanata
(NCBI TaxID 49450,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Associated disease: infection due to Digitalis lanata [ICD11:
XM2SP4 ]
NCBI PubMed ID: 8486748Publication DOI: 10.1016/0021-9673(93)80375-IJournal NLM ID: 0427043Publisher: Amsterdam: Elsevier
Institutions: Institut für Organische Chemie, Universität Tübingen, Germany, Pharmazeutisches Institut, Universität Tübingen, Tübingen, Germany
The separation of mixtures of primary and secondary cardiac glycosides by micellar electrokinetic capillary electrophoresis modified by cyclodextrins, urea and sodium cholate proved to be suitable for the determination of these hydrophobic compounds. It was possible to distinguish the two anomeric cardenolides glucodigifucoside and glucodigiglucomethyloside with all three buffer systems. Electropherograms of crude plant cell extracts from Digitalis lanata were obtained with this method.
Structure type: oligomer
Trivial name: lanatoside A
Compound class: saponin glycoside, glycoside, cardiac glycoside
Contained glycoepitopes: IEDB_142488,IEDB_146664,IEDB_983931,SB_192
Methods: MIKE, micellar electrokinetic chromatography
NCBI Taxonomy refs (TaxIDs): 49450Reference(s) to other database(s): CCSD:
48623, CBank-STR:8798
Show glycosyltransferases
There is only one chemically distinct structure:
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