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Structure type: oligomer
Compound class: O-antigen, glycoside, arabinan
Contained glycoepitopes: IEDB_1065879,IEDB_120354,IEDB_1309625,IEDB_134619,IEDB_857717,IEDB_857718

• Article ID: 5689
  Podvalnyy NM, Abronina PI, Fedina KG, Kondakov NN, Zinin AI, Chizhov AO, Torgov VI, Kachala VV, Kononov LO "Synthesis of hexasaccharide fragment of lipoarabonomannan from Mycobacteria: Advantages of the benzyl-free approach" - Izvestiia Akademii Nauk SSSR. Seriia khimicheskaia = Russian chemical bulletin [Russian] 64(5) (2015) 1149—1162
  

  Spacered branched hexaarabinofuranoside, which corresponds to the terminal fragment of mycobacterial lipoarabinomannan and arabinogalactan, was synthesized via three different routes. Synthetic scheme which involved only acyl and silyl protective groups (benzyl-free approach) allows one to reduce the number of deprotection steps, enhance the overall yield, and keep the azido group until the end of the synthesis

  lipoarabinomannan, 1, 2-cis-Glycosylation, arabinofuranose, benzyl-free approach

  Publication DOI: 10.1007/s11172-015-0992-5
  Journal NLM ID: 7505544
  Publisher: Moscow: Nauka
  Correspondence: Abronina PI ; Kononov LO
  Institutions: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
  Methods: 13C NMR, 1H NMR, NMR-2D, TLC, chemical synthesis, HPLC, GPC, UV, extraction, optical rotation measurement, column chromatography, HR-ESI-MS, 19F NMR
  
   
  
  Mycobacterium
  CSDB ID 49322 (all data & tools)