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Singh SB, Thakur RS, Schulten HR
Spirostanol saponins from Paris polyphylla, structures of polyphyllin C, D, E, and F
Phytochemistry 21 (1982)
2925-2929
Paris polyphylla
(NCBI TaxID 49666,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: tuber
The structure was elucidated in this paperPublication DOI: 10.1016/0031-9422(80)85070-9Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Institute of Physical Chemistry, University of Bonn, Bonn, West Germany, Central Institute of Medicinal and Aromatic Plants, Lucknow, India
The structures of four new saponins, polyphyllin C, D, E and F, isolated from the tubers of Paris polyphylla have been elucidated as diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)- [α-l-arabinofuranosyl(1→4)]-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl(1→3)]-β-d-glucopyranoside and diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l- rhamnopyranosyl(1→3)][β-d-glucopyranosyl(1→2)]-α-l-rhamnopyranoside, respectively, on the basis of chemical and spectral data.
diosgenin, saponins, Liliaceae, Paris polyphylia, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)[α-l-arabinofuranosyl(1→4)]β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)][α-l-rhamnopyranosyl(1→3)]-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl-(1→3)][β-D-glucopyranosyl(1→2)]α-l-rhamnopyranoside
Structure type: oligomer ; 745
C
39H
62O
12Location inside paper: Polyphyllin C, 1a
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_136105,IEDB_142488,IEDB_146664,IEDB_189517,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, IR, partial acid hydrolysis, TLC, acid hydrolysis, Smith degradation, alkaline hydrolysis, permethylation, PC, Kiliani hydrolysis, periodic oxidation
NCBI Taxonomy refs (TaxIDs): 49666Reference(s) to other database(s): CCSD:
27956, CBank-STR:3392
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There is only one chemically distinct structure:
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Singh SB, Thakur RS, Schulten HR
Spirostanol saponins from Paris polyphylla, structures of polyphyllin C, D, E, and F
Phytochemistry 21 (1982)
2925-2929
Paris polyphylla
(NCBI TaxID 49666,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: tuber
The structure was elucidated in this paperPublication DOI: 10.1016/0031-9422(80)85070-9Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Institute of Physical Chemistry, University of Bonn, Bonn, West Germany, Central Institute of Medicinal and Aromatic Plants, Lucknow, India
The structures of four new saponins, polyphyllin C, D, E and F, isolated from the tubers of Paris polyphylla have been elucidated as diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)- [α-l-arabinofuranosyl(1→4)]-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl(1→3)]-β-d-glucopyranoside and diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l- rhamnopyranosyl(1→3)][β-d-glucopyranosyl(1→2)]-α-l-rhamnopyranoside, respectively, on the basis of chemical and spectral data.
diosgenin, saponins, Liliaceae, Paris polyphylia, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)[α-l-arabinofuranosyl(1→4)]β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)][α-l-rhamnopyranosyl(1→3)]-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl-(1→3)][β-D-glucopyranosyl(1→2)]α-l-rhamnopyranoside
Structure type: oligomer ; 877
C
44H
70O
16Location inside paper: Polyphyllin D, 2a
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_136105,IEDB_136907,IEDB_142488,IEDB_146664,IEDB_189517,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, IR, partial acid hydrolysis, TLC, acid hydrolysis, Smith degradation, alkaline hydrolysis, permethylation, PC, Kiliani hydrolysis, periodic oxidation
NCBI Taxonomy refs (TaxIDs): 49666Reference(s) to other database(s): CCSD:
13118, CBank-STR:6172
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There is only one chemically distinct structure:
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Singh SB, Thakur RS, Schulten HR
Spirostanol saponins from Paris polyphylla, structures of polyphyllin C, D, E, and F
Phytochemistry 21 (1982)
2925-2929
|
a-L-Rhap-(1-3)-+
|
a-L-Rhap-(1-2)-a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Diosgenin |
Show graphically |
Paris polyphylla
(NCBI TaxID 49666,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: tuber
The structure was elucidated in this paperPublication DOI: 10.1016/0031-9422(80)85070-9Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Institute of Physical Chemistry, University of Bonn, Bonn, West Germany, Central Institute of Medicinal and Aromatic Plants, Lucknow, India
The structures of four new saponins, polyphyllin C, D, E and F, isolated from the tubers of Paris polyphylla have been elucidated as diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)- [α-l-arabinofuranosyl(1→4)]-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl(1→3)]-β-d-glucopyranoside and diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l- rhamnopyranosyl(1→3)][β-d-glucopyranosyl(1→2)]-α-l-rhamnopyranoside, respectively, on the basis of chemical and spectral data.
diosgenin, saponins, Liliaceae, Paris polyphylia, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)[α-l-arabinofuranosyl(1→4)]β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)][α-l-rhamnopyranosyl(1→3)]-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl-(1→3)][β-D-glucopyranosyl(1→2)]α-l-rhamnopyranoside
Structure type: oligomer ; 1037
C
51H
82O
20Location inside paper: Polyphyllin E, 4a
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_133754,IEDB_136105,IEDB_142488,IEDB_146664,IEDB_189517,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, IR, partial acid hydrolysis, TLC, acid hydrolysis, Smith degradation, alkaline hydrolysis, permethylation, PC, Kiliani hydrolysis, periodic oxidation
NCBI Taxonomy refs (TaxIDs): 49666Reference(s) to other database(s): CCSD:
13120, CBank-STR:9342
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There is only one chemically distinct structure:
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Singh SB, Thakur RS, Schulten HR
Spirostanol saponins from Paris polyphylla, structures of polyphyllin C, D, E, and F
Phytochemistry 21 (1982)
2925-2929
|
a-L-Rhap-(1-3)-+
|
b-D-Glcp-(1-2)-a-L-Rhap-(1-3)-Diosgenin
|
a-L-Rhap-(1-4)-+ |
Show graphically |
Paris polyphylla
(NCBI TaxID 49666,
species name lookup)
Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: tuber
The structure was elucidated in this paperPublication DOI: 10.1016/0031-9422(80)85070-9Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Institute of Physical Chemistry, University of Bonn, Bonn, West Germany, Central Institute of Medicinal and Aromatic Plants, Lucknow, India
The structures of four new saponins, polyphyllin C, D, E and F, isolated from the tubers of Paris polyphylla have been elucidated as diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)- [α-l-arabinofuranosyl(1→4)]-β-d-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl(1→3)]-β-d-glucopyranoside and diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l- rhamnopyranosyl(1→3)][β-d-glucopyranosyl(1→2)]-α-l-rhamnopyranoside, respectively, on the basis of chemical and spectral data.
diosgenin, saponins, Liliaceae, Paris polyphylia, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→3)[α-l-arabinofuranosyl(1→4)]β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→2)-α-l-rhamnopyranosyl(1→4)][α-l-rhamnopyranosyl(1→3)]-β-D-glucopyranoside, diosgenin-3-O-α-l-rhamnopyranosyl(1→4)[α-l-rhamnopyranosyl-(1→3)][β-D-glucopyranosyl(1→2)]α-l-rhamnopyranoside
Structure type: oligomer ; 1053
C
51H
82O
20Location inside paper: Polyphyllin F, 5a
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_136105,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_885823,IEDB_983931,SB_192
Methods: 1H NMR, IR, partial acid hydrolysis, TLC, acid hydrolysis, Smith degradation, alkaline hydrolysis, permethylation, PC, Kiliani hydrolysis, periodic oxidation
NCBI Taxonomy refs (TaxIDs): 49666Reference(s) to other database(s): CCSD:
13119, CBank-STR:8781
Show glycosyltransferases
There is only one chemically distinct structure:
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