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1. (Article ID: 1517)
Higson AP, Ross AJ, Tsvetkov YE, Routier FH, Sizova OV, Ferguson MAJ, Nikolaev AV
Synthetic Fragments of Antigenic Lipophosphoglycans from Leishmania major and Leishmania mexicana and Their Use for Characterisation of the Leishmania Elongating a-D-Mannopyranosylphosphate Transferase
Chemistry 11(7) (2005)
2019-2030
The phosphorylated branched heptasaccharides 7 and 8, the octasaccharide 9 and the phosphorylated trisaccharides 5 and 6, which are fragments of the phosphoglycan portion of the surface lipophosphoglycans from Leishmania mexicana (5) or L. major (6-9), were synthesised by using the glycosyl hydrogenphosphonate method for the preparation of phosphodiester bridges. The compounds were tested as acceptor substrates/putative inhibitors for the Leishmania elongating α-D-mannosylphosphate transferase.
transferase, fragment, antigenic, Synthetic, characterisation, use, leishmania, P, Leishmania mexicana
NCBI PubMed ID: 15685582Publisher: Vch Verlagsgesellschaft
Correspondence: a.v.nikolaev
dundee.ac.uk
Institutions: Faculty of Life Sciences Division of Biological Chemistry and Molecular Microbiology University of Dundee (Carnelley Building), Dundee DD1 4HN UK, N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow (Russia), Faculty of Life Sciences Division of Biological Chemistry and Molecular Microbiology University of Dundee (Wellcome Trust Building), Dundee DD1 5EH
Methods: chemical synthesis
The publication contains the following compound(s):
- Compound ID: 4089
|
b-D-Glcp-(1-3)-+
|
b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4090
|
b-D-Glcp-(1-3)-b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4086
|
b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4087
|
b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4088
|
b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4091
|
b-D-Galp-(1-3)-b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4092
|
b-D-Galp-(1-3)-+
|
b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4093
|
b-D-Galp-(1-3)-b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
- Compound ID: 4094
|
b-D-Galp-(1-3)-+
|
b-D-Galp-(1-3)-b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--6)--b-D-Galp-(1-4)-a-D-Manp-(1--P--1)--Dce-(?--/(CH2)8CH=CH2/
Dce = dec-9-enoic acid |
Show graphically |
Structure type: oligomer
Aglycon: (CH2)8CH=CH2
Compound class: lipophosphoglycan
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