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1. (Article ID: 1538)
 
Larsson EA, Sjoberg M, Widmalm G
Synthesis of oligosaccharides related to the repeating unit of the capsular polysaccharide from Streptococcus pneumoniae type 37
Carbohydrate Research 340(1) (2005) 7-13
 

A tetra- and a pentasaccharide were synthesized as analogues to the structure of the Streptococcus pneumoniae type 37 capsular polysaccharide, a homopolymer with a disaccharide-repeating unit of →3)[β-D-Glcp-(1→2)]-β-D-Glcp-(1→. Synthesis of the tetrasaccharide employed a β-(1→2)-diglycosylation of a β-(1→3)-linked disaccharide. Subsequently, the pentasaccharide was synthesized from a suitably protected tetrasaccharide derivative by a β-(1→3)-extension at O-3'. Steric crowding was found to be an important factor in the formation of the pentasaccharide

synthesis, oligosaccharide, structure, tetrasaccharide, chemistry, capsular, polysaccharide, Streptococcus, Streptococcus pneumoniae, repeating unit, Oligosaccharides, capsular polysaccharide, type, factor, derivative, formation, pentasaccharide, disaccharide, homopolymer, PDF, organic, analogue

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