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1. (Article ID: 1850)
Vinogradov EV, Knirel YA, Lipkind GM, Shashkov AS, Kochetkov NK, Stanislavsky ES, Kholodkova EV
Antigenic polysaccharides of bacteria. 23. The structure of the O-specific polysaccharide chain of the lipopolysaccharide of Salmonella arizonae O59
Bioorganicheskaya Khimia = Bioorganic Chemistry [Russian] 13 (1987)
1275-1281
The O-specific polysaccharide of Salmonella arizonae O59 (Arizona 19) is composed of D-galactose, N-acetyl-D-glucosamine, and N-acetyl-L-fucosamine (FucNAc, 2-acetamido-2,6-dideoxy-L-galactose) in the ratio 1:1:1. The computerized calculation of the 13C NMR spectrum of the polysaccharide, based on the monosaccharide composition, spectra of the free monosaccharides and glycosydation effects, together with the chemical analysis (methylation and Smith degradation) showed that the polysaccharide is built up of trisaccharide repeating units of the following structure: →3)-α-L-FucNAcp(1→3)-β-D-GlcNAcp-(1→2)-β-D-Galp-1(→. The molecular basis of serological interrelations between S. arizonae O59 and Pseudomonas aeruginosa O7 (Lányi) is discussed.
NCBI PubMed ID: 2447898Journal NLM ID: 7804941Publisher: Moskva: Nauka
Institutions: N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow, Russia
Methods: 13C NMR
The publication contains the following compound(s):
- Compound ID: 2542
Structure type: polymer chemical repeating unit
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G99900KO, GlycomeDB:
5649
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