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1. (Article ID: 1856)
 
Knirel YA, Zdorovenko GM, Shashkov AS, Yakovleva LM, Gubanova NY, Gvozdyak RI
Antigenic polysaccharides of bacteria. 29. Structure of the polysaccharide chain of the Pseudomonas holci 8300 (serogroup I) lipopolysaccharide
Bioorganicheskaya Khimia = Bioorganic Chemistry [Russian] 14(2) (1988) 172-179
 

The Pseudomonas holci 8300 lipopolysaccharide has an O-specific polysaccharide chain, containing L-rhamnose and 3-acetamido-3-deoxy-D-fucose residues in the ratio 4:1. On the basis of methylation, Smith degradation, and 1H- and 13C-NMR spectroscopy data, it was concluded that the polysaccharide is built up of pentasaccharide units of A and B types in the ratio approximately 2.5:1. In some stretches of the polysaccharide, minor B units form rather long chains, and in the others they alternate with predominant A units. (formula; see text)

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