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1. (Article ID: 1857)
Knirel YA, Zdorovenko GM, Shashkov AS, Mamyan SS, Gubanova NY, Yakovleva LM, Solyanik LP
Antigenic polysaccharides of bacteria. 30. Structure of the polysaccharide chain of the Pseudomonas syringae pv. syringae 281 (serogroup I) lipopolysaccharide
Bioorganicheskaya Khimia = Bioorganic Chemistry [Russian] 14(2) (1988)
180-186
Anomeric methyl 3-O-(D-mannopyranosyl- and L-rhamnopyranosyl)-β-D-talopyranosides were synthesised by the stereoselective 1,2-cis- and 1,2-trans manno- and rhamnosylation of methyl 2,4,6-tri-O-acetyl-β-D-talopyranoside, which has been prepared from methyl β-D-galactopyranoside by a synthetic scheme including conversion of the C2 configuration. From 13C-NMR spectra of the disaccharides obtained the spectral alpha- and beta-effects of O3-glycosylation of talopyranose were determined.
NCBI PubMed ID: 2454629Journal NLM ID: 7804941Publisher: Moskva: Nauka
Institutions: N.D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow, Russia
Methods: 13C NMR, 1H NMR
The publication contains the following compound(s):
- Compound ID: 1839
|
a-D-Fucp3NAc-(1-3)-+
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-3)-a-L-Rhap-(1-3)-a-L-Rhap-(1-2)-a-L-Rhap-(1-2)-a-L-Rhap-(1- |
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Structure type: polymer chemical repeating unit
Trivial name: L-rhamnan
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G53459KL, GlycomeDB:
37252
- Compound ID: 3564
|
a-D-Fucp3NAc-(1-3)-+
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a-L-Rhap-(1-3)-a-L-Rhap-(1-2)-a-L-Rhap-(1-2)-Gro |
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Structure type: oligomer
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G02315JP
- Compound ID: 4873
Structure type: oligomer
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G20028NV
- Compound ID: 4874
Structure type: oligomer
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G87391YH
- Compound ID: 1840
|
a-D-Fucp3NAc-(1-3)-+
|
-2)-a-L-Rhap-(1-3)-a-L-Rhap-(1-3)-a-L-Rhap-(1-3)-a-L-Rhap-(1- |
Show graphically |
Structure type: polymer chemical repeating unit
Compound class: O-polysaccharide, O-antigen
Reference(s) to other database(s): GTC:G34562NM, GlycomeDB:
25792
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