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1. (Article ID: 1866)
 
Knirel YA, Shashkov AS, Soldatkina MA, Zakharova IY
Antigenic polysaccharides of bacteria. 33. Structure of the O-specific polysaccharide chain of lipopolysaccharide from Pseudomonas cepacia serotype 6
Bioorganicheskaya Khimia = Bioorganic Chemistry [Russian] 14(10) (1988) 1413-1418
 

On mild acid degradation of the Pseudomonas cepacia serotype 6 lipopolysaccharide, the O-specific polysaccharide was obtained, which contains D-mannose and D-galactose residues in the ratio approximately 1:1, as well as O-acetyl groups. On the basis of 1H and 13C NMR analysis, calculation of specific optical rotation, and methylation, it was concluded that the polysaccharide possesses the following structure: (formula; see text) Regularities in glycosidation effects in 13C NMR spectra of 1,3-linked disaccharides containing furanoside residues are discussed.

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