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1. (Article ID: 1883)
 
Druzhinina TN, Streshinskaya GM, Goshadze MS, Shibaev VN, Naumova IB
Structural studies on the linkage unit between teichoic acid and peptidoglycan in cell wall of Streptomyces chrysomallus sp. 2 and biosynthesis of its tetrasaccharide fragment
Bioorganicheskaya Khimia = Bioorganic Chemistry [Russian] 17(5) (1991) 671-677
 

The linkage unit in ribitol teichoic acid of Streptomyces chrysomallus sp. 2 was purified and found to contain a tetrasaccharide, composed of GlcNAc, GalNAc, FucNAc and QuiNAc residues. The enzymic synthesis of polyprenyl pyrophosphate tetrasaccharide was performed using biosynthetic and synthetic uridine diphosphate aminohexoses. N-acetylglucosamine residue was identified at the reducing end of the tetrasaccharide. The synthetic derivatives QuiNAc - PPMpr and FucNAc - PPMpr could not serve as intermediates in the enzymic synthesis of the tetrasaccharide fragment.

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