One- and two-dimensional high resolution 'H and I3C nuclear magnetic resonance spectroscopy at 500 MHz and 125 MHz together with methylation and partial hydrolytic degradation methods were used to determine the structure of the antigenic O-polysaccharide produced by Actinobacillus (Haemophilus) pleuropneumoniae serotype 6 (ATCC 33590). The Opolysaccharide was shown to be a high molecular weight unbranched linear polymer of repeating pentasaccharide units having the structure: -3)-a-D-Glcp-(1-2)-b-D-Galf-(1-6)-a-D-Glcp-(1-6)-b-D-Glcp-(l-3)-b-D-Galf-(l-.
Lipopolysaccharide, nuclear magnetic resonance, Actinobacillus pleuropneumoniae, 0-antigen
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