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1. (Article ID: 197)
Vinogradov EV, Bock K, Petersen BO, Holst O, Brade H
The structure of the carbohydrate backbone of the lipopolysaccharide from Acinetobacter strain ATCC 17905
European Journal of Biochemistry 243(1-2) (1997)
122-127
The structure of the carbohydrate backbone of the lipopolysaccharide from Acinetobacter strain ATCC 17905 was studied. After deacylation of the lipopolysaccharide, a mixture of two compounds (ratio approximately 2:1) was isolated by high-performance anion-exchange chromatography, the structures of which were determined by NMR spectroscopy and electrospray-mass spectrometry as: [see formula in text] [Sug, 3-deoxy-D-manno-2-octulopyranosonic acid (Kdo) in oligosaccharide 1 (major portion) and D-glycero-D-talo-2-octulopyranosonic acid (Ko) in oligosaccharide 2 (minor portion)]. All monosaccharide residues also possess th D-cofiguration and are present in the pyranose form.
Lipopolysaccharide, NMR, Acinetobacter, core-lipid A region
NCBI PubMed ID: 9030730Journal NLM ID: 0107600Publisher: Oxford, UK: Blackwell Science Ltd. on behalf of the Federation of European Biochemical Societies
Institutions: Department of Chemistry, Carlsberg Laboratory, Copenhagen, Denmark, Division of Biochemical Microbiology, Center for Medicine und Biosciences, Research Center Borstel, Germany
Methods: NMR-2D, NMR, ESI-MS
The publication contains the following compound(s):
- Compound ID: 745
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a-D-Glcp-(1-6)-b-D-Glcp-(1-4)-a-D-Glcp-(1-5)-+ P-4)-+
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a-D-Glcp-(1-6)-b-D-Glcp-(1-3)-b-D-Galp-(1-7)-a-Kdop-(2-4)-a-Kdop-(2-6)-b-D-GlcpN-(1-6)-a-D-GlcpN-(1-P |
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Structure type: oligomer
Compound class: core oligosaccharide
Reference(s) to other database(s): GlycomeDB:
26678
- Compound ID: 746
|
a-D-Glcp-(1-6)-b-D-Glcp-(1-4)-a-D-Glcp-(1-5)-+ P-4)-+
| |
a-D-Glcp-(1-6)-b-D-Glcp-(1-3)-b-D-Galp-(1-7)-a-Kdop-(2-4)-a-Kop-(2-6)-b-D-GlcpN-(1-6)-a-D-GlcpN-(1-P |
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Structure type: oligomer
Compound class: core oligosaccharide
Reference(s) to other database(s): GlycomeDB:
26802
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