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Structure type: monomer ; 906.7403 [M-H]-
C₅₄H₁₀₁NO₉
Trivial name: asperiamide A
Compound class: cerebroside
Contained glycoepitopes: IEDB_142488,IEDB_146664,IEDB_983931,SB_192

• Article ID: 7803
  Ouyang MA, Liu R, Kuo YH "A new cerebroside, Asperiamide A, from the marine fungus Asperillus sp." - Journal of Asian Natural Products Research 7(5) (2005) 761-765
  

  A new cerebroside, asperiamide A, and adenosine were produced from a marine fungus, identified as Asperillus sp., collected in the Mei Zhou Gulf, China. Two-dimensional NMR methods, FAB-MS, were used to established the structure of the new compound.

  cerebroside, Marine fungus, Asperillus

  NCBI PubMed ID: 16176910
  Publication DOI: 10.1080/1028602042000324853
  Journal NLM ID: 100888334
  Publisher: Harwood Academic Publishers; London: Informa Healthcare
  Correspondence: maouyang@hqu.edu.cn
  Institutions: Department of Bio-engineering & Technology, Huaqiao University, Quanzhou, China, Department of Chemistry, Taiwan University, Taipei, Taiwan
  Methods: 13C NMR, 1H NMR, IR, FAB-MS, TLC, acid hydrolysis, extraction, optical rotation measurement, HPTLC, CC, cell growth
  
   
  
  Aspergillus sp. MF-34#
  CSDB ID 45689 (all data & tools)

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Structure type: monomer
Trivial name: phalluside-1
Compound class: cerebroside
Contained glycoepitopes: IEDB_137339,IEDB_142488,IEDB_146664,IEDB_983931,SB_192,SB_5

• Article ID: 7869
  Yang SX, Wang HP, Gao JM, Zhang Q, Laatsch H, Kuang Y "Fusaroside, a unique glycolipid from Fusarium sp., an endophytic fungus isolated from Melia azedarach" - Organic and Biomolecular Chemistry 10(4) (2012) 819-824
  

  Fusaroside (1), a unique trehalose-containing glycolipid composed of the 4-hydroxyl group of a trehalose unit attached to the carboxylic carbon of a long-chain fatty acid, was isolated from the organic extract of fermentation broths of an endophytic fungus, Fusarium sp. LN-11 isolated from the leaves of Melia azedarach. Six known compounds, phalluside (2), (9R*,10R*,7E)-6, 9,10-trihydroxyoctadec-7-enoic acid (3), porrigenic acid (4), (9Z)-2,3-dihydroxypropyl octadeca-9-enoate (5), cerevisterol (6) and ergokonin B (7), were also isolated from this fungus. The glycolipid contains a rare branched long-chain fatty acid (C(20:4)) with a conjugated diene moiety and a conjugated ketone moiety. The structure of the new compound 1 was elucidated by spectroscopic methods (1D and 2D NMR experiments, MS) and chemical degradations. The metabolites 1-5 were shown to have moderate to weak active against the brine shrimp larvae. To our knowledge, this is the first report of isolation of the first representative of a new family of glycolipids from natural sources.

  glycolipid, fusaroside, Fusarium sp., Melia azedarach

  NCBI PubMed ID: 22124543
  Publication DOI: 10.1039/c1ob06426f
  Journal NLM ID: 101154995
  Publisher: The Royal Society of Chemistry
  Correspondence: Gao JM ; Laatsch H
  Institutions: Department of Organic Chemistry, University of Göttingen, Göttingen, Germany, Chemical Biological Research Institute, College of Science, Northwest A&F University, Yangling, China, Department of Chemical Engineering, Huainan Union University, Huainan, China, Department of Crop Sciences, Georg-August-Universität Göttingen, Göttingen, Germany
  Methods: 13C NMR, 1H NMR, EI-MS, NMR-2D, IR, GC-MS, TLC, ESI-MS, biological assays, UV, extraction, optical rotation measurement, CC, reversed-phase chromatography, cell growth, HR-ESI-MS, derivatization
  
   
  
  Fusarium sp. LN-11
  CSDB ID 45943 (all data & tools)