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Structure type: monomer ; 630.2171 [M+Na]+, 608.2359 [M+H]+
C₃₀H₃₃N₅O₉
Trivial name: fumigatoside D
Compound class: glycoside

• Article ID: 8290
  Liu J, Wei X, Kim EL, Lin X, Yang XW, Zhou XF, Yang B, Jung JH, Liu YH "New glucosidated pyrazinoquinazoline indole alkaloids from fungus Aspergillus fumigatus derived of a jellyfish" - Tetrahedron 71(2) (2015) 271-275
  

  Three new pyrazinoquinazoline indole glucosides (1-3) were isolated from the fungus Aspergillus fumigatus derived from the jellyfish Nemopilema nomurai. Compounds 1-3 represent the first examples of glycosidated fumiquinzoline-type alkaloids from nature. The structures of the compounds were elucidated by spectroscopic methods and ECD/TDDFT calculations. A possible biogenetic pathway was proposed.

  Aspergillus fumigatus, pyrazinoquinazoline indole glucosides, jellyfish-derived, ECD/TDDFT

  Publication DOI: 10.1016/j.tet.2014.11.063
  Journal NLM ID: 2984170R
  Publisher: Pergamon Press
  Correspondence: Jung JH ; Liu YH
  Institutions: College of Pharmacy, Pusan National University, Busan, Korea, Key Laboratory of Tropical Marine Bio-resources and Ecology, South China Sea Institute of Oceanology, Chinese Academy of Sciences, Guangzhou, China, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou, China
  Methods: 13C NMR, 1H NMR, NMR-2D, IR, HPLC, extraction, optical rotation measurement, CD, CC, cell growth, HR-ESI-MS, antibacterial assay, cytotoxicity assay, DEPT, ECD
  
   
  
  Aspergillus fumigatus J08NF-8
  CSDB ID 47895 (all data & tools)