A glycan isolated from the surface-layer glycoprotein of Bacillus stearothermophilus strain NRS 2004/3a was shown by 1H- and 13C-n.m.r. spectroscopy to have the tetrasaccharide repeating-unit →4)-β-ManpA2,3(NAc)2-(1→3)-α-GlcpNAc-(1→4)-β- ManpA2,3(NAc)-(1→6)-α-Glcp(1→.
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