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Structure type: oligomer ; 955 [M-H]-
C₄₈H₇₅O₁₉
Trivial name: spinoside D1
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_136105,IEDB_141806,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_241101,IEDB_885823,IEDB_983931,SB_192

• Article ID: 10431
  Miyakoshi M, Ida Y, Isoda S, Shoji J "3-EPI-oleanene type triterpene glycosyl esters from leaves of Acanthopanax spinosus" - Phytochemistry 33 (1993) 891-895
  

  Three novel 3-epi-oleanene type triterpene oligo-glycosyl esters, spinosides D1–D3, were isolated from the leaves of Acanthopanax spinosus. The structures were established to be 28-O-α-l-rhamnopyranosyl(1→4)-β-d-glucopyranosyl(1→6)-β-d-glucopyranosyl esters of 3-epi-serratagenic acid, 3α-hydroxy-23-oxoolean-12-ene-28,29-dioic acid and 3α,23-dihydroxy-olean-12-ene-28,29-dioic acid.

  araliaceae, triterpenoid saponin, Acanthopanax spinosus, 3-epi-serratagenic acid, 3α, 23-dihydroxy-olean-12-ene-28, 29-dioic acid, 3α-hydroxy-23-oxoolean-12-ene-28, 3-epi-hederagenin

  Publication DOI: 10.1016/0031-9422(93)85298-6
  Journal NLM ID: 0151434
  Publisher: Elsevier
  Institutions: School of Pharmaceutical Sciences, Showa University, Tokyo, Japan
  Methods: 13C NMR, 1H NMR, gel filtration, IR, FAB-MS, reduction, PCD oxidation
  
   
  
  Acanthopanax spinosus
  CSDB ID 145976 (all data & tools)