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Structure type: oligomer
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_136105,IEDB_142488,IEDB_146664,IEDB_153543,IEDB_225177,IEDB_885823,IEDB_983931,SB_192

• Article ID: 10538
  Schopke T, Agha MIH, Wray V, Hiller K "Triterpenoid saponins from Bellium bellidioides" - Phytochemistry 36 (1994) 449-453
  

  A new acylated triterpenoid saponin carrying the rare 2,3-branched glucose at C-28 of the aglycone bayogenin (2β,3β,23-trihydroxyolean-12-en-28-oic acid) was isolated from the whole plants of Bellium bellidioides. The structure was elucidated mainly by high field NMR experiments (1H and 13C NMR, HMBC, HMQC, COSY-45 at 600/150 MHz) as 3-O-β-D-glucopyranosyl-28-O-[2-O-α-L-rhamnopyranosyl-3-O-β-D- glucopyranosyl-6-O-acetyl-β-D-glucopyranosyl]-23-O-acetylbayogenin . Additionally, three acylated derivatives of the known bellissaponin BS1 were obtained.

  NCBI PubMed ID: 7764882
  Journal NLM ID: 0151434
  Publisher: Elsevier
  Institutions: Humboldt-Universität zu Berlin, Fachbereich Pharmazie, Berlin, F.R.G
  
   
  
  Bellium bellidioides
  CSDB ID 146303 (all data & tools)

Show legend Show as text

Structure type: oligomer
Trivial name: bellissaponin BS1, besysaponin C14
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_114701,IEDB_136105,IEDB_142489,IEDB_149135,IEDB_167188,IEDB_174332,IEDB_225177,IEDB_885823,SB_86

• Article ID: 10538
  Schopke T, Agha MIH, Wray V, Hiller K "Triterpenoid saponins from Bellium bellidioides" - Phytochemistry 36 (1994) 449-453
  

  A new acylated triterpenoid saponin carrying the rare 2,3-branched glucose at C-28 of the aglycone bayogenin (2β,3β,23-trihydroxyolean-12-en-28-oic acid) was isolated from the whole plants of Bellium bellidioides. The structure was elucidated mainly by high field NMR experiments (1H and 13C NMR, HMBC, HMQC, COSY-45 at 600/150 MHz) as 3-O-β-D-glucopyranosyl-28-O-[2-O-α-L-rhamnopyranosyl-3-O-β-D- glucopyranosyl-6-O-acetyl-β-D-glucopyranosyl]-23-O-acetylbayogenin . Additionally, three acylated derivatives of the known bellissaponin BS1 were obtained.

  NCBI PubMed ID: 7764882
  Journal NLM ID: 0151434
  Publisher: Elsevier
  Institutions: Humboldt-Universität zu Berlin, Fachbereich Pharmazie, Berlin, F.R.G
  
   
  
  Bellium bellidioides
  CSDB ID 146304 (all data & tools)
• Article ID: 10893
  Schopke T, Hiller K, Wray V, Köppel KD, Yamasaki K, Kasai R "Triterpenoid saponins from Bellis sylvestris, I. Structures of the major deacylsaponins" - Journal of Natural Products 57 (1994) 1279-1282
  

  Two major saponins from Bellis sylvestris have been isolated and their structures determined, mainly by high-field nmr spectroscopy. One of these [2] was identical with bellissaponin BS1 from Bellis perennis, while the second is a new triterpenoid saponin [1], named besysaponin C12, and identified as 3-O-α-L-rhamnopyranosyl-2β,3β,16α,23-tetrahydroxyolean-12-en-28-oic acid 28-O-β-D-xylopyranosyl(1→4)-α-L-rhamnopyranosyl(1→2)-β-D- fucopyranoside.

  NCBI PubMed ID: 7798963
  Publication DOI: 10.1021/np50111a016
  Journal NLM ID: 7906882
  Publisher: American Society of Pharmacognosy
  Institutions: Humboldt-Universität zu Berlin, Fachbereich Pharmazie, Germany
  
   
  
  Bellis sylvestris
  CSDB ID 140902 (all data & tools)