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Taxonomic group: bacteria / Proteobacteria (Phylum: Proteobacteria)

The structure was elucidated in this paper
Publication DOI: 10.1080/00021369.1985.10867075
Journal NLM ID: 0370452
Publisher: Tokyo: Agricultural Chemical Society Of Japan
Institutions: Institute of Applied Microbiology, The University of Tokyo, Microbiology, Bunkyo-ku, Tokyo 113, Japan

The structure of latosillan was elucidated by a degradative study and NMR spectral analysis. This revealed that latosillan is a heteroglycan composed of repeating units of the pentasaccharide, →2)-β-d-Man-(1→2)-{β-d-G1CNAC-(1→4)}.-α-l-Rha-(1→4)-α-l-Rha-(1→4)-α-l-Rha-(1→, shown in Fig. 1.

NMR, structure, differentiation, Alcaligenes, Latosillan, leukemia

Structure type: polymer chemical repeating unit
Location inside paper: abstract,p.2443
Trivial name: latosillan
Compound class: EPS
Contained glycoepitopes: IEDB_135813,IEDB_136105,IEDB_137340,IEDB_137485,IEDB_141807,IEDB_144983,IEDB_151531,IEDB_152206,IEDB_225177,IEDB_885823,IEDB_983930,SB_44,SB_72

Methods: 13C NMR, 1H NMR, methylation, partial acid hydrolysis, sugar analysis, acid hydrolysis, GPC, GCL

NCBI Taxonomy refs (TaxIDs): 45677
Reference(s) to other database(s): GTC:G68553CX, GlycomeDB:763
Show glycosyltransferases

There is only one chemically distinct structure:

[*]O[C@@H]1[C@H](O[C@H]2[C@H](O[C@H]3[C@H](C)O[C@@H](O[C@H]4[C@H](C)O[C@@H]([*])[C@H](O)[C@@H]4O)[C@H](O)[C@@H]3O)O[C@@H](C)[C@H](O[C@@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3NC(C)=O)[C@H]2O)O[C@H](CO)[C@@H](O)[C@@H]1O

SVG MW SMILES 3D mol Ionize