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Found 2 structures. Displayed structures from 1 to 2
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1. Compound ID: 27491

Compound 27491

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Structure type: oligomer ; 889 [M-H]-
C₄₄H₇₄O₁₈
Trivial name: trigoneside IIb
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_114701,IEDB_142488,IEDB_146664,IEDB_167188,IEDB_174332,IEDB_983931,SB_192

The structure is contained in the following publication(s):

Article ID: 11036
Yoshikawa M, Murakami T, Komatsu H, Murakami N, Yamahara J, Matsuda H "Medicinal foodstuffs. IV. Fenugreek seed. (1): Structures of trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb, new furostanol saponins from the seeds of Indian Trigonella foenum-graecum L." - Chemical and Pharmaceutical Bulletin 45 (1997) 81-87

Six new furostanol saponins called trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb were isolated from a medicinal foodstuff, fenugreek seed, the seed of Trigonella foenum-graecum L. (Leguminosae) originating from India, together with two known saponins, glycoside D and trigofoenoside A. The structures of trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb were determined on the basis of chemical and physicochemical evidence as 26-O-β-D-glucopyranosyl-(25S)-5α-furostane-2α,3β,22ξ,26-tetraol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-2α,3β,22ξ,26-tetraol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5β-furostane-3β,22ξ,26-triol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5 β-furostane-3β,22ξ,26-triol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25S)-5α-furostane-3β,22ξ,26-triol 3-O-[α-L-rhamnopyranosyl(1→2)]-β-D-glucopyranoside, and 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-3β,22ξ,26-triol 3-O-[α-L-rhamnopyranosyl(1→2)]-β-D-glucopyranoside, respectively.
medicinal foodstuff, Leguminosae, fenugreek, furostanol saponin, Trigonella foenum-graecum, trigoneoside
NCBI PubMed ID: 9023970
Publication DOI: 10.1248/cpb.45.81
Journal NLM ID: 0377775
WWW link: http://ci.nii.ac.jp/naid/110003616372
Publisher: Pharmaceutical Society Of Japan
Institutions: Kyoto Pharmaceutical University, Kyoto, Japan
Methods: 13C NMR, 1H NMR, NMR-2D, IR, FAB-MS, sugar analysis, TLC, acid hydrolysis, chemical methods, NMR-1D, methanolysis, HPLC, extraction, CC

Trigonella foenum-graecum
CSDB ID 271774 (all data & tools)

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2. Compound ID: 28159

Compound 28159

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Structure type: oligomer ; 913 [M+Na]+; 889 [M-H]-
C₄₄H₇₄O₁₈
Trivial name: trigoneoside IIb
Compound class: saponin glycoside
Contained glycoepitopes: IEDB_114701,IEDB_142488,IEDB_146664,IEDB_167188,IEDB_174332,IEDB_983931,SB_192

The structure is contained in the following publication(s):

Article ID: 11036
Yoshikawa M, Murakami T, Komatsu H, Murakami N, Yamahara J, Matsuda H "Medicinal foodstuffs. IV. Fenugreek seed. (1): Structures of trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb, new furostanol saponins from the seeds of Indian Trigonella foenum-graecum L." - Chemical and Pharmaceutical Bulletin 45 (1997) 81-87

Six new furostanol saponins called trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb were isolated from a medicinal foodstuff, fenugreek seed, the seed of Trigonella foenum-graecum L. (Leguminosae) originating from India, together with two known saponins, glycoside D and trigofoenoside A. The structures of trigoneosides Ia, Ib, IIa, IIb, IIIa, and IIIb were determined on the basis of chemical and physicochemical evidence as 26-O-β-D-glucopyranosyl-(25S)-5α-furostane-2α,3β,22ξ,26-tetraol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-2α,3β,22ξ,26-tetraol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5β-furostane-3β,22ξ,26-triol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25R)-5 β-furostane-3β,22ξ,26-triol 3-O-[β-D-xylopyranosyl(1→6)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-(25S)-5α-furostane-3β,22ξ,26-triol 3-O-[α-L-rhamnopyranosyl(1→2)]-β-D-glucopyranoside, and 26-O-β-D-glucopyranosyl-(25R)-5α-furostane-3β,22ξ,26-triol 3-O-[α-L-rhamnopyranosyl(1→2)]-β-D-glucopyranoside, respectively.
medicinal foodstuff, Leguminosae, fenugreek, furostanol saponin, Trigonella foenum-graecum, trigoneoside
NCBI PubMed ID: 9023970
Publication DOI: 10.1248/cpb.45.81
Journal NLM ID: 0377775
WWW link: http://ci.nii.ac.jp/naid/110003616372
Publisher: Pharmaceutical Society Of Japan
Institutions: Kyoto Pharmaceutical University, Kyoto, Japan
Methods: 13C NMR, 1H NMR, NMR-2D, IR, FAB-MS, sugar analysis, TLC, acid hydrolysis, chemical methods, NMR-1D, methanolysis, HPLC, extraction, CC

Trigonella foenum-graecum L
CSDB ID 60646 (all data & tools)

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