A new isoflav-3-ene, 2,2′-dimethoxy-7-hydroxy-4′,5′-methylenedioxyisoflav-3-ene (2-methoxyjudaicin), has been isolated from the roots of Cicer bijugum. The structure was determined by NMR spectroscopy and FAB-mass spectrometry. Chromatographic and mass spectral data indicate that this isoflav-3-ene is also present in the plant as a glycoside.
roots, Leguminosae, Cicer bijugum, wild chickpeas, isoflav-3-ene, 2-methoxyjudaicin
Publication DOI: 10.1016/S0031-9422(96)00757-1Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Jodrell Laboratory, Royal Botanic Gardens, Kew, Richmond, Surrey TW9 3DS, U.K.
Methods: 13C NMR, 1H NMR, FAB-MS, chemical methods, HPLC, UV, extraction