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Structure type: monomer ; 449 [M-H]-
C₂₁H₂₂O₁₁
Trivial name: hovetrichoside C
Compound class: glycoside
Contained glycoepitopes: IEDB_142488,IEDB_146664,IEDB_983931,SB_192

• Article ID: 11491
  Yoshikawa K, Eiko K, Mimura N, Kondo Y, Arihara S "Hovetrichosides C-G, five new glycosides of two auronols, two neolignans, and a phenylpropanoid from the bark of Hovenia trichocarea" - Journal of Natural Products 61(6) (1998) 786-790
  

  Two 2-hydroxy-2-benzylcoumaranone glycosides, 2,4,6-trihydroxy-2-[(4'- hydroxyphenyl) methyl]3(2H)-benzofuranone-4-yl-β-D-glucopyranoside (maesopsin 4-O-glucoside) (1) and 2,4,6-trihydroxy-2-[(4'-hydroxyphenyl) methyl]-3(2H)-benzofuranone-4-yl-β-D-glucopyranosido-4'-yl-α- Lrhamnopyranoside (maesopsin 4-O-glucosido 4'-O-rhamnoside) (2), two neolignan glycosides, 2R-(E)-2,3-dihydro-2-(4'hydroxy-3'-methoxylphenyl)-5- (3'-hydroxy-1'-propenyl)-7-methoxy-3-benzofuranmethanol-4'yl-β-D- glucopyranosyl-(1→3)-[β-D-glucopyranosyl-(→2)]-β-D-glucopyranoside (3) and (threo) 1-(4'-hydroxy-3'-methoxy)-2-(4-hydroxymethyl-2,6- dimethoxyphenoxy)propane-1,3-diol-4'-yl-β-D-glucopynoside (4), and a phenylpropanoid glycoside, 3-methoxy-5(2'-propenyl)-1,2-benzenediol-1-ylβ- D-apiofuranosyl-(1→6)-β-D-glucopyranoside (5) were isolated from the bark of Hovenia trichocarea. Compounds 1-5 were named hovetricosides C-G, respectively, and their structures were established by extensive NMR experiments and chemical methods. Also obtained in this investigation were the known compounds acanthoside B, kelampayoside A, shashenoside I, and 3,4,5-trimethoxyphenol-1-O-β-D-xylopyranosyl-(1→6)β-D-glucopyranoside.

  Carbohydrate Sequence, Molecular Sequence Data, hydrolysis, Magnetic Resonance Spectroscopy, glycosides, plant epidermis, high pressure liquid chromatography

  NCBI PubMed ID: 9644065
  Publication DOI: 10.1021/np9800396
  Journal NLM ID: 7906882
  Publisher: American Society of Pharmacognosy
  Institutions: Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima, Japan
  Methods: 13C NMR, 1H NMR, NOE, FAB-MS, acid hydrolysis, HPLC, UV, extraction, optical rotation measurement, CD, CC, melting point determination, HMBC, FT-IR
  
   
  
  Hovenia trichocarea
  CSDB ID 61983 (all data & tools)

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Structure type: oligomer ; 595 [M-H]-
C₂₇H₃₂O₁₅
Trivial name: hovetrichoside D
Compound class: glycoside
Contained glycoepitopes: IEDB_136105,IEDB_142488,IEDB_146664,IEDB_225177,IEDB_885823,IEDB_983931,SB_192

• Article ID: 11491
  Yoshikawa K, Eiko K, Mimura N, Kondo Y, Arihara S "Hovetrichosides C-G, five new glycosides of two auronols, two neolignans, and a phenylpropanoid from the bark of Hovenia trichocarea" - Journal of Natural Products 61(6) (1998) 786-790
  

  Two 2-hydroxy-2-benzylcoumaranone glycosides, 2,4,6-trihydroxy-2-[(4'- hydroxyphenyl) methyl]3(2H)-benzofuranone-4-yl-β-D-glucopyranoside (maesopsin 4-O-glucoside) (1) and 2,4,6-trihydroxy-2-[(4'-hydroxyphenyl) methyl]-3(2H)-benzofuranone-4-yl-β-D-glucopyranosido-4'-yl-α- Lrhamnopyranoside (maesopsin 4-O-glucosido 4'-O-rhamnoside) (2), two neolignan glycosides, 2R-(E)-2,3-dihydro-2-(4'hydroxy-3'-methoxylphenyl)-5- (3'-hydroxy-1'-propenyl)-7-methoxy-3-benzofuranmethanol-4'yl-β-D- glucopyranosyl-(1→3)-[β-D-glucopyranosyl-(→2)]-β-D-glucopyranoside (3) and (threo) 1-(4'-hydroxy-3'-methoxy)-2-(4-hydroxymethyl-2,6- dimethoxyphenoxy)propane-1,3-diol-4'-yl-β-D-glucopynoside (4), and a phenylpropanoid glycoside, 3-methoxy-5(2'-propenyl)-1,2-benzenediol-1-ylβ- D-apiofuranosyl-(1→6)-β-D-glucopyranoside (5) were isolated from the bark of Hovenia trichocarea. Compounds 1-5 were named hovetricosides C-G, respectively, and their structures were established by extensive NMR experiments and chemical methods. Also obtained in this investigation were the known compounds acanthoside B, kelampayoside A, shashenoside I, and 3,4,5-trimethoxyphenol-1-O-β-D-xylopyranosyl-(1→6)β-D-glucopyranoside.

  Carbohydrate Sequence, Molecular Sequence Data, hydrolysis, Magnetic Resonance Spectroscopy, glycosides, plant epidermis, high pressure liquid chromatography

  NCBI PubMed ID: 9644065
  Publication DOI: 10.1021/np9800396
  Journal NLM ID: 7906882
  Publisher: American Society of Pharmacognosy
  Institutions: Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima, Japan
  Methods: 13C NMR, 1H NMR, NOE, FAB-MS, acid hydrolysis, HPLC, UV, extraction, optical rotation measurement, CD, CC, melting point determination, HMBC, FT-IR
  
   
  
  Hovenia trichocarea
  CSDB ID 62127 (all data & tools)