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Taxonomic group: fungi / Ascomycota (Phylum: Ascomycota)

The structure was elucidated in this paper
NCBI PubMed ID: 21523866
Publication DOI: 10.1002/anie.201008258
Journal NLM ID: 0370543
Publisher: Weinheim: Wiley-VCH
Correspondence: Laurence.Barron

glasgow.ac.uk
Institutions: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden, Department of Chemistry, University of Glasgow, Glasgow, UK

glycosylation, glycoproteins, invertase, Raman optical activity

Structure type: oligomer
Location inside paper: scheme 1, a-D-Manp-OMe, M2M, M2M2M
Compound class: mannan
Contained glycoepitopes: IEDB_130701,IEDB_136104,IEDB_140116,IEDB_141830,IEDB_143632,IEDB_144983,IEDB_152206,IEDB_983930,SB_136,SB_196,SB_44,SB_67,SB_72

Methods: 13C NMR, 1H NMR, NMR-2D, ESI-MS, chemical synthesis, Raman spectroscopy
Synthetic data: chemical
Comments, role: glycan structure of intact yeast external invertase; m/z (M2M2M)= 541.1754 [M+Na]+

Related record ID(s): 43443, 43444, 43445
NCBI Taxonomy refs (TaxIDs): 4932
Show glycosyltransferases

There is only one chemically distinct structure:

CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O

SVG MW SMILES 3D mol Ionize