Taxonomic group: plant / Streptophyta
(Phylum: Streptophyta)
Organ / tissue: aerial part
The structure was elucidated in this paperPublication DOI: 10.1248/cpb.47.561Journal NLM ID: 0377775Publisher: Pharmaceutical Society Of Japan
Institutions: Department of Pharmacognosy, Faculty of Pharmacy, Hacettepe University, Ankara, Turkey, Department of Pharmacognosy, Faculty of Pharmaceutical Sciences, Nagoya City University, Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Nizuho-ku, Nagoya 467-8603 Japan
Fushioside, a new phenylethanoid glucoside, 2-(3,4-dihydroxyphenyl)ethyl 6-O-protocatechuoyl-β-D-glucopyranoside was isolated from the methanolic extract of the aerial parts of Veronica fuhsii along with a known phenylethanoid glycoside, plantamajoside, and a flavone glucoside, luteolin 7-O-glucoside.
phenylethanoid glycoside, Scrophulariaceae, Veronica fuhsii, fuhsioside
Structure type: monomer ; 452
C
21H
24O
11Location inside paper: compound 3, table 1
Trivial name: fuhsioside
Compound class: phenylethanoid glucoside
Contained glycoepitopes: IEDB_142488,IEDB_146664,IEDB_983931,SB_192
Methods: 13C NMR, 1H NMR, IR, FAB-MS, UV, HMBC, HMQC, COSY
Comments, role: NMR temperature was not specified
Related record ID(s): 63382, 63383
NCBI Taxonomy refs (TaxIDs): 388490
Show glycosyltransferases
NMR conditions: in CD3OD
[as TSV]
13C NMR data:
Linkage Residue C1 C2 C3 C4 C5 C6 C7 C8
8,6 xXPrcat 122.5 117.5 146.1 151.7 115.8 123.8 168.1
8 bDGlcp 104.4 74.9 77.8 71.7 75.4 64.7
xX3,4,8HOPhet 131.3 117.0 145.9 144.5 116.3 121.2 36.5 72.2
1H NMR data:
Linkage Residue H1 H2 H3 H4 H5 H6 H7 H8
8,6 xXPrcat - 7.45 - - 6.77 7.44 -
8 bDGlcp 4.32 3.22 3.39 3.39 3.55 4.40-4.56
xX3,4,8HOPhet - 6.64 - - 6.63 6.48 3.69 2.76
1H/13C HSQC data:
Linkage Residue C1/H1 C2/H2 C3/H3 C4/H4 C5/H5 C6/H6 C7/H7 C8/H8
8,6 xXPrcat 117.5/7.45 115.8/6.77 123.8/7.44
8 bDGlcp 104.4/4.32 74.9/3.22 77.8/3.39 71.7/3.39 75.4/3.55 64.7/4.40-4.56
xX3,4,8HOPhet 117.0/6.64 116.3/6.63 121.2/6.48 36.5/3.69 72.2/2.76
1H NMR data:
| Linkage | Residue | H1 | H2 | H3 | H4 | H5 | H6 | H7 | H8 |
|---|
| 8,6 | xXPrcat |
| 7.45 |
|
| 6.77 | 7.44 |
| |
| 8 | bDGlcp | 4.32 | 3.22 | 3.39 | 3.39 | 3.55 | 4.40
4.56 | |
| | xX3,4,8HOPhet |
| 6.64 |
|
| 6.63 | 6.48 | 3.69 | 2.76 |
|
13C NMR data:
| Linkage | Residue | C1 | C2 | C3 | C4 | C5 | C6 | C7 | C8 |
|---|
| 8,6 | xXPrcat | 122.5 | 117.5 | 146.1 | 151.7 | 115.8 | 123.8 | 168.1 | |
| 8 | bDGlcp | 104.4 | 74.9 | 77.8 | 71.7 | 75.4 | 64.7 | |
| | xX3,4,8HOPhet | 131.3 | 117.0 | 145.9 | 144.5 | 116.3 | 121.2 | 36.5 | 72.2 |
|
There is only one chemically distinct structure:
Found 
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