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1. (Article ID: 7226)
 
Gao JM, Hu L, Dong ZJ, Liu JK
New glycosphingolipid containing an unusual sphingoid base from the basidiomycete Polyporus ellisii
Lipids 36(5) (2001) 521-527
 

A new 9-methyl-sphinga-4,8-dienine-containing glucocerebroside (1), together with two additional known analogs, cerebrosides B and D, was isolated from the chloroform-soluble lipid fraction of the ethanol and chloroform/methanol extract of the fruiting bodies of the basidiomycete Polyporus ellisii Berk. and characterized. The structure and relative stereochemistry of the new compound were identified as (25,3R,4E,8E)-I -(β-D-glucopyranosyl)-3-hydroxy-2-[(R)-2′hydroxyheptadecanoyl] amino-9-methyl-4,8-octadecadiene by means of spectroscopic (1H, 13C, and two-dimensional nuclear magnetic resonance; mass spectrometry) and chemical methods.

glycosphingolipid, cerebroside, Polyporus ellisii

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