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1. (Article ID: 9166)
Kopp B, Krenn L, Kubelka E, Kubelka W
Cardenolides from Adonis aestivalis
Phytochemistry 31(9) (1992)
3195-3198
Four cardenolides were isolated for the first time from the aerial parts of Adonis aestivalis. The compounds were identified by spectrometry and for 3-epi-periplogenin, helveticoside also by comparison with authentic substances. Two new cardenolides were structurally elucidated: strophanthidin-3-O-β-D-digitoxosido-α-L-cymarosido-β-D-glucoside and strophanthidin-3-O-β-D-digitoxosido-β-D-digoxoside-β-D-diginosido-β-D-glucoside.
cardiac glycosides, Adonis aestivalis, Ranunculaceae, cardenolides, strophanthidin, 3-epi-periplogenin, helveticoside, strophanthidin-3-O-β-D-digitoxosido-α-L-cymarosido-β-D-glucoside, strophanthidin-3-O-β-D-digitoxosido-β-D-digoxoside-β-D-diginosido-β-D-glucoside
NCBI PubMed ID: 1368415Publication DOI: 10.1016/0031-9422(92)83473-cJournal NLM ID: 0151434Publisher: Elsevier
Institutions: Institute of Pharmacognosy, University of Vienna, Vienna, Austria
Methods: 13C NMR, 1H NMR, methylation, FAB-MS, GC-MS, TLC, acid hydrolysis, GLC, HPLC, extraction, CC, derivatization
The publication contains the following compound(s):
- Compound ID: 22348
|
b-D-Digp-(1-3)-Subst
Subst = strophanthidin = SMILES C[C@]12CC[C@H]3[C@@H](CC{5}[C@@]4(O)[C@]3(C=O)CC{3}[C@H](O)C4){14}[C@@]1(O)CC[C@@H]2C5=CC(OC5)=O |
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Structure type: monomer
; 535 [M+H]+
Trivial name: helveticoside
Compound class: saponin glycoside, glycoside
- Compound ID: 22349
|
b-D-Glcp-(1-4)-a-L-Digp3Me-(1-4)-b-D-Digp-(1-3)-Subst
Subst = strophanthidin = SMILES C[C@]12CC[C@H]3[C@@H](CC{5}[C@@]4(O)[C@]3(C=O)CC{3}[C@H](O)C4){14}[C@@]1(O)CC[C@@H]2C5=CC(OC5)=O |
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Structure type: oligomer
; 841 [M+H]+
Compound class: saponin glycoside, glycoside
- Compound ID: 22350
|
b-D-Glcp-(1-4)-b-D-2,6dlyxHexp3Me-(1-4)-b-D-Digp-(1-4)-b-D-Digp-(1-3)-Subst
Subst = strophanthidin = SMILES C[C@]12CC[C@H]3[C@@H](CC{5}[C@@]4(O)[C@]3(C=O)CC{3}[C@H](O)C4){14}[C@@]1(O)CC[C@@H]2C5=CC(OC5)=O |
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Structure type: oligomer
; 971 [M+H]+
Compound class: saponin glycoside, glycoside
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