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1. (Article ID: 9750)
Mori Y, Kawasaki T
New diosgenin glycoside, aspidistrin, from Aspidistra elatior Blume
Chemical and Pharmaceutical Bulletin 21(1) (1973)
224-227
Journal NLM ID: 0377775Publisher: Pharmaceutical Society Of Japan
Institutions: Faculty of Pharmaceutical Sciences, Fukuoka University, Japan, Faculty of Pharmaceutical Sciences, Kyushu University, Japan
Methods: IR, NMR, TLC, acid hydrolysis, MS, enzymatic digestion
The publication contains the following compound(s):
- Compound ID: 23724
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b-D-Xylp-(1-3)-+
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b-D-Glcp-(1-2)-b-D-Glcp-(1-4)-b-D-Galp-(1-3)-Diosgenin |
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Structure type: oligomer
Trivial name: aspidistrin
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
40125, CBank-STR:12099
- Compound ID: 23725
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b-D-Xylp-(1-3)-+
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b-D-Glcp-(1-2)-b-D-Glcp-(1-4)-b-D-Galp-(1-3)-Subst
Subst = tigogenin = SMILES [H][C@]1(O[C@@]2(OC[C@H](C)CC2)[C@H]3C)C[C@@]4([H])[C@]5([H])CC[C@@]6([H])C{3}[C@@H](O)CC[C@]6(C)[C@@]5([H])CC[C@]4(C)[C@]13[H] |
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Structure type: oligomer
Trivial name: desgalactotigonin, desgalactotigonin sativoside, uttronin A, desgalactotigogenin, deagalactotigonin
Compound class: saponin glycoside, glycoside
Reference(s) to other database(s): CCSD:
27160, CBank-STR:12103
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2. (Article ID: 10927)
Damtoft S, Frederiksen LB, Jensen SR
Biosynthesis of iridoid glucosides in Thunbergia alata
Phytochemistry 37 (1994)
1599-1603
Deoxy-[6,7,8,10-2H] loganic acid and 8-epideoxy-[6,7,8, 10-2 H] loganic acid were fed to Thunbergia alata. The former was incorporated into stilbericoside with retention of the label at H-6, H-7 and H-8. Administration of deuterium-labelled loganic acid, adoxosidic acid, capensioside and 8(S)-bisdeoxy-7,8-dihydroaucubin showed that the first steps in the biosynthesis of stilbericoside from deoxyloganic acid are most probably lo-hydroxylation followed by decarboxylation.
biosynthesis, iridoid glucosides, Thunbergia alata, Acanthaceae, stilbericoside, 2H NMR
Publication DOI: 10.1016/S0031-9422(00)89574-6Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Department of Organic Chemistry, The Technical University of Denmark, Lyngby, Denmark
Methods: 13C NMR, 1H NMR, TLC, HPLC, MPLC, radiolabelling
The publication contains the following compound(s):
- Compound ID: 27218
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D-Glcp-(1-1)-Subst
Subst = capensioside aglycon = SMILES O{1}[C@@H]1[C@@]2([H])[C@@](CC[C@@H]2{10}CO)([H])C=CO1 |
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Structure type: monomer
Trivial name: capensioside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
49863, CBank-STR:337
- Compound ID: 27219
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D-Glcp-(1-1)-Subst11Me
Subst = SMILES O={11}C(C1=CO{1}[C@H](O)[C@@]2([H])[C@]1([H])C(C[C@@H]2C)=O)O |
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Structure type: monomer
Trivial name: cornin
Compound class: glycoside
Reference(s) to other database(s): CCSD:
49863, CBank-STR:337
- Compound ID: 27220
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D-Glcp-(1-1)-Subst
Subst = thunaloside aglycon = SMILES O{1}[C@@H]1[C@@]2([H])[C@](C{7}[C@H](O)[C@@H]2{8}CO)([H])C=CO1 |
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Structure type: monomer
Trivial name: thunaloside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
49863, CBank-STR:337
- Compound ID: 27221
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D-Glcp-(1-1)-Subst
Subst = stilbericoside aglycon = SMILES O{1}[C@@H]1[C@@]2([H]){5}[C@@]({6}[C@H](O)[C@@]3([H])[C@]2([H])O3)(O)C=CO1 |
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Structure type: monomer
Trivial name: stilbericoside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
49864, CBank-STR:347
- Compound ID: 27222
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D-Glcp-(1-1)-Subst
Subst = 6-epistilbericoside aglycon = SMILES O{1}[C@@H]1[C@@]2([H]){5}[C@@]({6}[C@@H](O)[C@@]3([H])[C@]2([H])O3)(O)C=CO1 |
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Structure type: monomer
Trivial name: 6-epistilbericoside
Compound class: glycoside
Reference(s) to other database(s): CCSD:
49866, CBank-STR:353
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