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1. (Article ID: 9758)
 
Tomoda M, Kimura S
Plant mucilages. XII. Fourteen oligosaccharides obtained from Bletilla-glucomannan by partial acetolysis
Chemical and Pharmaceutical Bulletin 24 (1976) 1807-1812
 

Partial acetolysis of Bletilla-glucomannan, the mucilage from the tubers of Bletilla striata REICHENBACH fil., has led to the isolations of fourteen oligosaccharides. Analysis of components, methylation and partial degradation studies provided the evidences that they are O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, O-α-D-mannopyranosyl-(1→4)-D-mannopyranose, O-β-D-mannopyranosyl-(1→4)-D-glucopyranose, O-β-D-glucopyranosyl-(1→4)-D-mannopyranose, O-β-D-glucopyranosyl-(1→4)-D-glucopyranose, O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, O-β-D-glucopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-glucopyranose, O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-glucopyranose, O-β-D-mannopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→4)-D-mannopyranose, O-β-D-glucopyranosyl-O-β-D-glucopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, O-β-D-glucopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose, and O-β-D-mannopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→4)-O-β-D-mannopyranosyl-(1→4)-D-mannopyranose. Among them, it is conceivable that mannobiose having α-glycosidic linkage is the artifact produced during the reaction.

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2. (Article ID: 11021)
 
Usui T, Mizuno T, Kato K, Tomoda M, Miyajima G
Carbon-13 NMR spectra of glucomannooligosaccharides and structurally related glucomannan
Agricultural and Biological Chemistry 43 (1979) 863-865
 
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