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1. (Article ID: 9773)
Kobayashi Y, Takeda T, Ogihara Y
New triterpenoid glycosides from the leaves of Bupleurum rotundifolium L
Chemical and Pharmaceutical Bulletin 29(8) (1981)
2222-2229
Two new triglycosides of oleanane-type triterpenes, rotundioside E (3) and F (1), isolated from the leaves of Bupleurum rotundifolium L. were identified as 16α,28-dihydroxyoleana-11,13(18)-dien-3β-yl α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl-(1→2)-β-D-fucopyranoside (3) and 13β,28-epoxy-16α-hydroxyoleana-11-en-3β-yl α-L-rhamnopyranosyl-(1→2)-β-D-glucopyranosyl-(1→2)-β-D-fucopyranoside (1), respectively, on the basis of chemical and spectroscopic evidence.
oleanane triterpenoid glycoside, Bupleurum rotundifolium L., Umbelliferae, rotundioside E, rotundioside F, CMR spectrum, Smith-de Mayo degradation
Journal NLM ID: 0377775WWW link: http://ci.nii.ac.jp/naid/110003633966Publisher: Pharmaceutical Society Of Japan
Institutions: Faculty of Pharmaceutical Sciences, Nagoya City University, Nagoya, Japan
Methods: IR, TLC, acid hydrolysis, MS, methylation analysis, melting point determination, PMR, acetylation analysis, CMR, Smith-de Mayo degradation
The publication contains the following compound(s):
- Compound ID: 23800
|
a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-b-D-Fucp-(1-3)-Subst
Subst = rotundiogenin A = SMILES CC1(C){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])C=C[C@]45[C@]6([H])CC(C)(C)CC[C@@](CO5)6{16}[C@H](O)C[C@](C)4[C@@](C)3CC[C@@]12[H] |
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Structure type: oligomer
Trivial name: rotundioside F
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
15440, CBank-STR:7615
- Compound ID: 23801
|
a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-b-D-Fucp-(1-3)-Subst
Subst = rotundiogenin B = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])C=CC4=C5CC(C)(C)CC[C@]5({28}CO){16}[C@H](O)C[C@@]4(C)[C@]3(C)CC[C@@]2([H])C1(C)C |
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Structure type: oligomer
Trivial name: rotundioside E
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
15440, CBank-STR:7615
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2. (Article ID: 10945)
Xiong Q, Shi D, Mizuno M
Flavonol glucosides in pericarps of Zanthoxylum bungeanum
Phytochemistry 39 (1995)
723-725
Two new flavonol glucosides, viz. quarcetin 3′,4′-dimethyl ether 7-glucoside and tamarixetin 3,7-bis-glucoside, together with hyperin, quercetin, quercitrin, foeniculin, isorhamnetin 7-glucoside, rutin, 3,5,6-trihydroxy-7,4′-dimethoxyflavone, arbutin, sitosterol β-glucoside, l-sesamin and palmitic acid were isolated from the pericarps of Zanthoxylum bungeanum. Their structures were established by spectroscopic and spectrophotometric methods.
pericarp, Zanthoxylum bungeanum, flavonol glycosides, Rutaceae, quercetin 3′, 4′-dimethyl ether 7-glucoside, tamarixetin 3, 7-bis-glucoside
Publication DOI: 10.1016/0031-9422(94)00965-VJournal NLM ID: 0151434Publisher: Elsevier
Institutions: Department of Pharmacognosy, Gifu Pharmaceutical University, Gifu, Japan, Department of Pharmacognosy, School of Pharmacy, Shanghai Medical University, Shanghai, China
Methods: 13C NMR, 1H NMR, UV, CC
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