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1. (Article ID: 9883)
Kawai H, Nishida M, Tashiro Y, Kuroyanagi M, Ueno A, Satake M
Studies on the structures of udosaponins A,B,C,D,E, and F from Aralia cordata Thunb
Chemical and Pharmaceutical Bulletin 37(9) (1989)
2318-2321
Six new triterpenoid saponins, named udosaponins A, B, C, D, E, and F, were isolated as methyl esters, 2,6,7,8,9 and 11,respectively, along with five kinown saponins as methyl esters, 1,3,4,5 and 10,from the aerial parts of Aralia cordata THUNB. (Araliaceae). On the basis of 13C-nuclear magnetic resonance spectra and chemical evidence, these saponins were established to be oleanane-type saponins having a glucuronopyranosyl residue at the C-3 position of oleanolic acid and hederagenin.
13C-NMR, hederagenin, araliaceae, oleanolic acid, saponon, Aralia cordata, udosaponin, A-value
Journal NLM ID: 0377775WWW link: http://ci.nii.ac.jp/naid/110003627990Publisher: Pharmaceutical Society Of Japan
Institutions: School of Pharmaceutical Sciences, University of Shizuoka, Shizuoka-shi, Japan, Tsukuba Medicinal Plants Research Station, National Institue of Hygienic Sciences, Tsukuba-shi, Japan
Methods: 13C NMR, 1H NMR, FAB-MS, partial acid hydrolysis, methanolysis, alkaline hydrolysis, UV, CD, methylation analysis
The publication contains the following compound(s):
- Compound ID: 24040
|
b-D-Xylp-(1-4)-b-D-GlcpA6Me-(1-3)-Oleanolic28Me
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: udosaponin A
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
1269, CBank-STR:4057
- Compound ID: 24041
|
b-D-GlcpA6Me-(1-3)-Oleanolic28Me
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: rivularinin
Compound class: saponin glycoside
- Compound ID: 24042
|
b-D-Glcp-(1-28)-+
|
b-D-GlcpA6Me-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24043
|
b-D-Galp-(1-2)-b-D-GlcpA6Me-(1-3)-Oleanolic28Me
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24044
|
b-D-Glcp-(1-28)-+
|
b-D-Xylp-(1-4)-b-D-GlcpA6Me-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24045
|
b-D-Glcp-(1-28)-+
|
b-D-Galp-(1-2)-b-D-GlcpA6Me-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: udosaponin B
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
1271, CBank-STR:8814
- Compound ID: 24046
Structure type: oligomer
Trivial name: udosaponin D
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
1272, CBank-STR:4058
- Compound ID: 24047
|
b-D-Glcp-(1-28)-+
|
b-D-Xylp-(1-4)-b-D-GlcpA6Me-(1-3)-Hederagenin |
Show graphically |
Structure type: oligomer
Trivial name: udosaponin D
Compound class: saponin glycoside
- Compound ID: 24048
Structure type: oligomer
Trivial name: udosaponin E
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
1273, CBank-STR:5469
- Compound ID: 24049
|
b-D-Glcp-(1-28)-+
|
b-D-Galp-(1-2)-b-D-GlcpA6Me-(1-3)-Hederagenin |
Show graphically |
Structure type: oligomer
Trivial name: udosaponin F
Compound class: saponin glycoside, triterpenoid glycoside
Reference(s) to other database(s): CCSD:
1280, CBank-STR:8816
- Compound ID: 24050
|
b-D-Glcp-(1-28)-+
|
b-D-Xylp-(1-4)-+ |
| |
b-D-Galp-(1-2)-b-D-GlcpA6Me-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: udosaponin C
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
20142, CBank-STR:12215
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