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1. (Article ID: 9901)
Wu F, Koike K, Ohimoto T, Chen W
Saponins from Chinese folk medicine, 'Zhu jie xiang fu,' Anemone raddeana Regel
Chemical and Pharmaceutical Bulletin 37(9) (1989)
2445-2447
From the Chinese folk medicine "Zhu jie xian fu" (roots of Anemone raddeana REGEL, Ranunculaceae), two new oleanane-type glycosides, named raddeanosides R8 (1) and R9 (2), were isolated. The structures of 1 and 2 were determined as 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranosyl-(1→2)-α-L-arabinopyranosyl oleanolic acid 28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside and 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranosyl-(1→2)-α-L-arabinopyranosyl 27-hydroxyolenolic acid 28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-β-D-glucopyranoside, respectively.
Ranunculaceae, saponin, Chinese folk medicine, Anemone raddeana, raddeanoside R8, raddeanoside R9, Zhu jie xian fu, oleanane-type glycoside
Journal NLM ID: 0377775WWW link: http://ci.nii.ac.jp/naid/110003628014Publisher: Pharmaceutical Society Of Japan
Institutions: Chengdu Institute of Biology, Academia Sinica, Shichuan, China, School of Pharmaceutical Sciences, Toho University, Chiba, Japan
Methods: 13C NMR, 1H NMR, IR, FAB-MS, methanolysis, HPLC
The publication contains the following compound(s):
- Compound ID: 24070
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a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-2)-b-D-Glcp-(1-28)-Subst
Subst = 27-hydroxyoleanolic acid = SMILES O{3}[C@H]1CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])CC(C)(C)CC[C@@]({28}C(O)=O)5CC[C@]({27}CO)4[C@@](C)3CC[C@]([H])2C1(C)C |
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Structure type: oligomer
Trivial name: raddeanoside R8
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
1286, CBank-STR:14696
- Compound ID: 24071
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a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-a-L-Arap-(1-3)-+
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a-L-Rhap-(1-4)-b-D-Glcp-(1-6)-b-D-Glcp-(1-28)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
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Structure type: oligomer
Trivial name: raddeanoside R8
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
20144, CBank-STR:14695
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2. (Article ID: 10397)
Wu F, Chu T
Chemical constituents of the Chinese medicinal herb Anemone raddeana Regel. Part V
Hua Xue Xue Bao = Acta Chimica Sinica [Chinese] 43 (1985)
82-86
Journal NLM ID: 0111476Publisher: Peking, Ke xue chu ban she
The publication contains the following compound(s):
- Compound ID: 25388
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a-L-Rhap-(1-4)-b-D-Glcp-(1-28)-+
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a-L-Rhap-(1-2)-b-D-Glcp-(1-2)-a-L-Arap-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
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Structure type: oligomer
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
27651, CBank-STR:12672
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