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1. (Article ID: 9930)
Masood M, Minocha PK, Tiwari KP, Srivastava KC
Narcissiflorine, narcissiflorinine, and narcissifloridine, three triterpene saponins from Anemone narcissiflora
Phytochemistry 20 (1981)
1675-1679
Narcissiflorine, narcissiflorinine and narcissifloridine, three new saponins, have been isolated from the ethanolic extract of Anemone narcissiflora (Ranunculaceae). The structural elucidation of narcissiflorine, narcissiflorinine and narcissifloridine has showed them to be [α-l-arabinofuranosyl-(1→4)-β-d-glucuronopyranosyl-(1→3)]- 3β-hydroxy-olean-12-en-28-oic acid, [α,-l-arabinofuranosyl-(1→2)-α-l-rhamnopyranosyl-(1→4)-β-d- glucuronypyranosyl(1→3)]-3-β-hydroxy-olean-12-en-28-oic acid and [α-l-arabinofuranosyl-(1→2)-α-l- rhamnopyranosyl-(1→4)-β-d-glucopyranosyl-(1→3)]-3-β-hydroxy-olean-12-en-28-oic acid, respectively.
saponins, Ranunculaceae, Anemone narcissiflora, narcissiflorine, narcissiflorinine, narcissifloridine, oleanolic acid derivatives
Publication DOI: 10.1016/S0031-9422(00)98553-4Journal NLM ID: 0151434Publisher: Elsevier
Institutions: Department of Chemistry, University of Allahabad, Allahabad, India, Department of Community Health and Social Medicine, Hygiejnisk Institute, Odense University, Odense, Denmark
Methods: periodate oxidation, IR, partial acid hydrolysis, TLC, acid hydrolysis, colorimetry, permethylation
The publication contains the following compound(s):
- Compound ID: 24124
|
a-L-Araf-(1-2)-a-L-Rhap-(1-4)-b-D-GlcpA-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: narcissiflorinine
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
13097, CBank-STR:6198
- Compound ID: 24125
|
a-L-Araf-(1-4)-b-D-GlcpA6Me-(1-3)-Oleanolic28Me
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24126
|
a-L-Araf-(1-4)-b-D-Glcp-(1-3)-Subst
Subst = olean-12-en-3β,28-diol = SMILES CC1(C){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])CC(C)(C)CC[C@@]({28}CO)5CC[C@](C)4[C@@](C)3CC[C@@]12[H] |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24127
|
a-L-Araf-(1-4)-b-D-GlcpA-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Trivial name: narcissiflorine, tarasaponin VI (prochikusetsusaponin IV), chikusetsusaponin Ib
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
48846, CBank-STR:3225
- Compound ID: 24128
|
a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Subst
Subst = olean-12-en-3β,28-diol = SMILES CC1(C){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])CC(C)(C)CC[C@@]({28}CO)5CC[C@](C)4[C@@](C)3CC[C@@]12[H] |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24129
|
a-L-Rhap-(1-4)-b-D-GlcpA-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24130
|
a-L-Araf-(1-2)-a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Subst
Subst = olean-12-en-3β,28-diol = SMILES CC1(C){3}[C@@H](O)CC[C@]2(C)[C@@]3([H])CC=C4[C@]5([H])CC(C)(C)CC[C@@]({28}CO)5CC[C@](C)4[C@@](C)3CC[C@@]12[H] |
Show graphically |
Structure type: oligomer
Trivial name: narcissifloridine
Compound class: saponin glycoside
Reference(s) to other database(s): CCSD:
13098, CBank-STR:6143
- Compound ID: 24131
|
a-L-Araf-(1-2)-a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Oleanolic
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
- Compound ID: 24132
|
a-L-Araf-(1-2)-a-L-Rhap-(1-4)-b-D-Glcp-(1-3)-Oleanolic28Me
Oleanolic = 3β-hydroxyolean-12-en-28-oic acid |
Show graphically |
Structure type: oligomer
Compound class: saponin glycoside
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